Publication

Prof. Dr. Hirohisa Ohmiya

Original publications

  1. Markovnikov Selective Hydroamination of Aliphatic Alkenes with Anilines and Azoles through a Light-Driven Multiple Catalysis
    1. Kishida, N.; Kobayashi, R.; Nakagawa, M.; Nagao, K.; Ohmiya, H.
    2. Bull. Chem. Soc. Jpn. 2026, 99, in press.
    3. DOI: 10.1093/bulcsj/uoag021
  2. Machine-learning-guided Screening of Organic Photosensitizers Accelerated by Domain Adaptation
    1. Ikemura, H.; Noto, N.; Akiba, R.; Rohlfs, T.; Masuda, Y.; Sumida, Y.; Mancheño, O. G.; Hosoya, T.; Ohmiya, H.; Sawamura, M.; Saito, S.
    2. Cell Rep. Phys. Sci. 2026, 7, in press.
  3. A Dual Photoredox/Cobalt Catalytic System enables Markovnikov-Selective Hydroaminoalkylation of Alkenes
    1. Takekawa, Y.; Geniller, L.; Nagao, K; Ohmiya, H.
    2. Precis. Chem. 2026, 4, in press (Special Issue on Precision Control of Single-Electron Reactions).
    3. DOI: 10.1021/prechem.5c0038
  4. Carbonylative Ring Expansion of Cyclic Carboxylic Acids
    1. Shimono, H.; Kusakabe, M.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2025, 147, 45884–45892.
    3. DOI: 10.1021/jacs.5c08640
    4. Most Read Articles (1 month)
    5. ChemRxiv. 2025
    6. DOI: 10.26434/chemrxiv-2025-0856
  5. Deep-Red to Near-Infrared Light-Driven Radical Generation from Organoboron Compounds via Ligand-Induced Direct Excitation Catalysis
    1. Miyamoto, Y.; Muraoka, K.;  Murakami, S.; Matsudaira, T.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2025, 147, 41185–4119.
    3. DOI: 10.1021/jacs.5c17266
  6. Photocatalyzed Synthesis of Unsymmetrical Alkylphosphorus(V) Compounds Using Imidazolium Phosphonites
    1. Ota, K.; Fujiwara, Y.; Nagao, K.; Ohmiya, H.
    2. Angew. Chem. Int. Ed. 2025, 64, e202502803.
    3. DOI: 10.1002/anie.202502803
  7. N‑Heterocyclic Carbene/Organic Photoredox-Cocatalyzed Acyl Azolation of Alkenes with Acyl Azoles
    1. Togishi, K.; Goto, Y.; Murakami, S.; Ohmiya, H.
    2. Org. Lett. 2025, 27, 5760–5764.
    3. DOI: 10.1021/acs.orglett.5c01533
  8. Organophotoredox-Catalyzed Postfunctionalization of Poly(methacrylate) Derivatives via Radical–Polar Crossover Phosphonylation
    1. Tamano, T.; Sato, K.; Ohmiya, H.; Inagi, S.
    2. Angew. Chem. Int. Ed. 2025, 64, e202507572
    3. DOI: 10.1002/anie.202507572
  9. Para-Selective C–H Alkylation of Aroyl Chlorides through Organic Photoredox-Catalyzed Radical tele-Substitution
    1. Oya, R.; Sato, H.; Nagao, K.; Ohmiya, H.
    2. Chem 2025, 11, 102446.
    3. DOI: 10.1016/j.chempr.2025.102446
  10. Distal C–H Functionalization of Alkoxyarenes through Organic Photoredox-Catalyzed Radical–Radical Coupling
    1. Goto, Y.; Ohmiya, H.
    2. Chem. Sci. 2025, 16, 4320–4327.
    3. DOI: 10.1039/D4SC08407A
  11. Photoredox-Catalyzed Site-Selective Intermolecular C(sp3)–H Alkylation of Tetrahydrofurfuryl Alcohol Derivatives
    1. Abe, R.; Nagao, K.; Seki, T.; Hata, D.; Sasaki, Y.; Ohmiya, H.
    2. Org. Lett. 2025, 27, 795–801.
    3. DOI: 10.1021/acs.orglett.4c04439
  12. Organic Photoredox-Catalyzed Unimolecular PCET of Benzylic Alcohols
    1. Matsuo, T.; Sano, M.; Sumida, Y.; Ohmiya, H.
    2. Chem. Sci. 2025, 16, 3150–3156.
    3. DOI: 10.1039/D4SC07048H
  13. Radical C-Glycosylation Using Photoexcitable Unprotected Glycosyl Borate
    1. Miyamoto, Y.; Murakami, S.; Sumida, Y.; Hirai, G.; Ohmiya, H.
    2. Chem. Eur. J. 2024, 30, e202402256.
    3. DOI: 10.1002/chem.202402256
  14. Deoxygenative Geminal Silylboration of Amides Using Silylboronates: Synthesis and Use of α-Boryl-α-Silylalkylamines
    1. Watanabe, K.; Nagao, K.; Ohmiya, H.
    2. Angew. Chem. Int. Ed. 2024, 63, e202411990.
    3. DOI: 10.1002/anie.202411990
    4. ChemRxiv. 2024
    5. DOI: 10.26434/chemrxiv-2024-55nn
  15. γ-Amino C(sp3)–H Functionalization of Aliphatic Amines through a Light-Driven Triple Catalysis
    1. Nakagawa, M.; Nagao, K.; Ohmiya, H.
    2. ACS Catal. 2024, 14, 8005–8012.
    3. DOI: 10.1021/acscatal.4c0200
    4. Most Read Articles (1 month)
  16. Use of Aliphatic Carboxylic Acid Derivatives for NHC/Photoredox-Catalyzed meta-Selective Acylation of Electron-Rich Arenes
    1. Goto, Y.; Murakami, S.; Sumida, Y.; Ohmiya, H.
    2. Synthesis 2024, 56, 3327–3333 (Special Issue 10th Pacific Symposium on Radical Chemistry (PSRC-10)).
    3. DOI: 10.1055/a-2281-2975
  17. A Dual Cobalt and Photoredox Catalysis for Hydrohalogenation of Alkenes
    1. Shibutani, S.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2024, 146, 4375–4379.
    3. DOI: 10.1021/jacs.3c10133
    4. Most Read Articles (1 month)
    6. Kyoto univ. press release
  18. Synthesis of Tertiary Alkylphosphonate Oligonucleotides through Light-Driven Radical-Polar Crossover Reactions
    1. Ota, K.; Nagao, K.; Hata, D.; Sugiyama, H.; Segawa, Y.; Tokunoh, R.;  Seki, T.; Miyamoto, N.; Sasaki, Y.; Ohmiya, H.
    2. Nat. Commun. 2023, 14, 6856.
    3. DOI: 10.1038/s41467-023-42639-y
    5. Kyoto univ. and IMS press release
  19. Biomimetic Design of an a-Ketoacylphosphonium-Based Light-Activated Oxygenation Auxiliary
    1. Oya, R.; Ota, K.; Fuki, M.; Kobori, Y.; Higashi, M.; Nagao, K.; Ohmiya, H.
    2. Chem. Sci. 2023, 14, 10488–10493.
    3. DOI: 10.1039/D3SC03572G
  20. Diastereoselective Congested β-Amido Ketone Synthesis via NHC-Catalyzed Radical–Radical Coupling
    1. Sato, Y.; Miyamoto, Y.; Matsui, T.; Sumida, Y.; Ohmiya, H.
    2. Chem Catal. 2023, 3, 100736.
    3. DOI: 10.1016/j.checat.2023.100736
    4. ChemRxiv. 2023
    5. DOI: 10.26434/chemrxiv-2023-wbm3p
  21. N-Heterocyclic Carbene- and Organic Photoredox-Catalysed meta-Selective Acylation of Electron-Rich Arenes
    1. Goto, Y.; Sano, M.; Sumida, Y.; Ohmiya, H.
    2. Nat. Synth. 2023, 2, 1037–1045.
    3. DOI: 10.1038/s44160-023-00378-4
    4. ChemRxiv. 2023
    5. DOI: 10.26434/chemrxiv-2023-1p1kv-v2
    7. Kyoto univ. and JST press release    Highlighted in Synform
  22. A Quadruple Catalysis Enabling Intermolecular Branch-Selective Hydroacylation of Styrenes
    1. Takekawa, Y.; Nakagawa, M.; Nagao, K.; Ohmiya, H.
    2. Chem. Eur. J. 2023, 29, e202301484 (Very Important Papers).
    3. DOI: 10.1002/chem.202301484
  23. Radical Caging Strategy for Cholinergic Optopharmacology
    1. Nakamura, R.; Yamazaki,T.; Kondo, Y.; Tsukada, M.; Miyamoto,Y.; Arakawa,N.; Sumida, Y.; Kiya, T.; Arai, S.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2023, 145, 10651–10658.
    3. DOI: 10.1021/jacs.3c00801
    5. Kyoto univ. and Kanazawa univ. press release
  24. Light-Driven Radical-Polar Crossover Catalysis Enabling Decarboxylative Fluorination of Redox Active Esters
    1. Takekawa, Y.; Kodo, T.; Nagao, K.; Kakei, H.; Takeuchi, K.; Sasaki, Y.; Ohmiya, H.
    2. Chem. Lett. 2023, 52, 41–43.
    3. DOI: 10.1246/cl.220472
  25. Light-Driven Radical-Polar Crossover Catalysis for Cross-Coupling with Organosilanes
    1. Matsuo, T.; Nagao, K.; Ohmiya, H.
    2. Tetrahedron Lett. 2022, 112, 154231 (Special Issue on “Recent Advances in Photocatalysis for Selective Organic Synthesis”).
    3. DOI: 10.1016/j.tetlet.2022.154231
  26. Organic Photoredox-Catalyzed Silyl Radical Generation from Silylboronate
    1. Takemura, N.; Sumida, Y.; Ohmiya, H.
    2. ACS Catal. 2022, 12, 7804–7810.
    3. DOI: 10.1021/acscatal.2c01964
    4. Most Read Articles (1 month)
  27. Direct Photoexcitable Iodomethylborate Enabling Cyclopropanation of Reactive Alkenes
    1. Nakamura, R.; Sumida, Y.; Ohmiya, H.
    2. Bull. Chem. Soc. Jpn. 2022 , 95, 1001–1005 (Selected Paper).
    3. DOI: 10.1246/bcsj.20220112
  28. Organophotoredox-Catalyzed Semipinacol Rearrangement via Radical-Polar Crossover
    1. Kodo, T.; Nagao, K.; Ohmiya, H.
    2. Nat. Commun. 2022, 13, 2684.
    3. DOI: 10.1038/s41467-022-30395-4
    5. Kyoto univ., Kanazawa univ. and JST press release
  29. A Triple Photoredox/Cobalt/Bronsted Acid Catalysis Enabling Markovnikov Hydroalkoxylation of Unactivated Alkenes
    1. Nakagawa, M.; Matsuki, Y.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2022, 144, 7953–7959.
    3. DOI: 10.1021/jacs.2c00527
    4. Most Read Articles (1 month)
    6. Kyoto univ. and Kanazawa univ. press release   EurekAlert!
  30. Reductive Cross-Coupling between Arylaldehydes and (Hetero)aryl Electrophiles Using Silylboronate Reductant
    1. Watanabe, K.; Takeda, M.; Nagao, K.; Ohmiya, H.
    2. Eur. J. Org. Chem. 2022, e202200005 (Virtual Special Collection on “Silicon Chemistry in Organic Synthesis”).
    3. DOI: 10.1002/ejoc.202200005
  31. Molecular Field Analysis Using Computational-Screening Data in Asymmetric N-Heterocyclic Carbene-Copper Catalysis toward Data-driven in silico Catalyst Optimization
    1. Mukai, M.; Nagao, K.; Yamaguchi, S.; Ohmiya, H.
    2. Bull. Chem. Soc. Jpn. 2022 , 95, 271–277 (Selected Paper).
    3. DOI: 10.1246/bcsj.20210349
    5. Riken and Kanazawa univ. press release
  32. Direct Photoexcitation of Borate Enabling Minisci Reaction
    1. Kemmochi, M.; Miyamoto, Y.; Sumida, Y.; Ohmiya, H.
    2. Asian. J. Org. Chem. 2022, 11, e202100640 (AsianJOCs 10th Anniversary Special Collection).
    3. DOI: 10.1002/ajoc.202100640
  33. Light-Driven N-Heterocyclic Carbene Catalysis Using Alkylborates
    1. Sato, Y.; Goto, Y.; Nakamura, K.; Miyamoto, Y.; Sumida, Y.; Ohmiya, H.
    2. ACS Catal. 2021, 11, 12886–12892.
    3. DOI: 10.1021/acscatal.1c04153
    4. Most Read Articles (1 month)
  34. Radical Relay Trichloromethylacylation of Alkenes through N-Heterocyclic Carbene Catalysis
    1. Kusakabe, M.; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 7242–7247.
    3. DOI: 10.1021/acs.orglett.1c02639
  35. Organophotoredox-Catalyzed Decarboxylative N-Alkylation of Sulfonamides
    1. Nakagawa, M.; Nagao, K.; Ikeda, Z.; Reynolds, M.; Ibáñez, I.; Wang, J.; Tokunaga, N.; Sasaki, Y.; Ohmiya, H.
    2. ChemCatChem 2021, 13, 3930–3933 (part of a joint Special Collection with EurJIC on “Main Group Catalysis”)
    3. DOI: 10.1002/cctc.202100803
  36. Generation of Functionalized Alkyl Radicals via the Direct Photoexcitation of 2,2′-(Pyridine-2,6-diyl)diphenol-Based Borates
    1. Miyamoto, Y.; Sumida, Y.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 5865–5870.
    3. DOI: 10.1021/acs.orglett.1c01996
    4. Most Read Articles (1 month)
  37. Aryl Radical-Mediated N-Heterocyclic Carbene Catalysis
    1. Matsuki, Y.; Ohnishi, N.; Kakeno, Y.; Takemoto, S.; Ishii, T.; Nagao, K.; Ohmiya, H.
    2. Nat. Commun. 2021, 12, 3848.
    3. DOI: 10.1038/s41467-021-24144-2
    5. Kanazawa univ. and JST press release   EurekAlert!　Asian Research News　Science Japan
  38. Decarboxylative N-Alkylation of Azoles Through Visible-Light-Mediated Organophotoredox Catalysis
    1. Kobayashi, R.; Shibutani, S.; Nagao, K.; Ikeda, Z.; Wang, J.; Ibáñez, I.; Reynolds, M.; Sasaki, Y.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 5415–5419 (Supplementary Cover ).
    3. DOI: 10.1021/acs.orglett.1c01745
    4. Most Read Articles (1 month)
  39. Synthesis of Sterically Hindered α-Hydroxycarbonyls through Radical–Radical Coupling
    1. Ota, K.; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 4420–4425.
    3. DOI: 10.1021/acs.orglett.1c01358
    4. Most Read Articles (1 month)
  40. Radical N-Heterocyclic Carbene Catalysis for β-Ketocarbonyl Synthesis
    1. Ishii, T.; Nagao, K.; Ohmiya, H.
    2. Tetrahedron 2021, 91, 132212 (Special Issue on System-Oriented Development of Organocatalysis).
    3. DOI: 10.1016/j.tet.2021.132212
  41. Fluorescent-oxaboroles: Synthesis and Optical Property by Sugar Recognition
    1. Nakano, M.; Nakamura, R.; Sumida, Y.; Nagao, K.; Furuyama, T.; Inagaki, F.; Ohmiya, H.
    2. Chem. Pharm. Bull. 2021, 69, 526–528 (Featured Article).
    3. DOI: 10.1248/cpb.c21-00179
    4. Most viewed articles Jun.2021
  42. Catalytic Reductive Cross-Coupling between Aromatic Aldehydes and Arylnitriles
    1. Mitsui, A.; Nagao, K.; Ohmiya, H.
    2. Chem. Eur. J. 2021, 27, 7094–7098.
    3. DOI: 10.1002/chem.202100763
  43. Organophotoredox-Catalyzed Three-Component Coupling of Heteroatom Nucleophiles, Alkenes, and Aliphatic Redox Active Esters
    1. Shibutani, S.; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 1798-1803.
    3. DOI: 10.1021/acs.orglett.1c00211
    4. Most Read Articles (1 month)
  44. Transition-Metal-Free Cross-Coupling by Using Tertiary Benzylic Organoboronates
    1. Takeda, M.; Nagao, K.; Ohmiya, H.
    2. Angew. Chem. Int. Ed. 2020, 59, 22460–22464.
    3. DOI: 10.1002/anie.202010251
    5. EurekAlert!
  45. Boracene-Based Alkylborate Enabling Ni/Ir Hybrid Catalysis
    1. Sato, Y.; Miyamoto, Y.; Sumida, Y.; Hosoya, T.; Ohmiya, H.
    2. Org. Biomol. Chem. 2020, 18, 6598–6601 (Themed Issue on Hybrid Catalysis).
    3. DOI: 10.1039/D0OB01610A
  46. Direct Synthesis of Dialkyl Ketones from Aliphatic Aldehydes through Radical N-Heterocyclic Carbene Catalysis
    1. Kakeno, Y.; Kusakabe, M.; Nagao, K.; Ohmiya, H.
    2. ACS Catal. 2020, 10, 8524–8529.
    3. DOI: 10.1021/acscatal.0c02849
    4. Most Read Articles (1 month)
    6. Kanazawa univ. and JST press release   EurekAlert!　Asian Research News
  47. Reductive Umpolung for Asymmetric Synthesis of Chiral α-Allenic Alcohols
    1. Kondo, Y.; Nagao, K.; Ohmiya, H.
    2. Chem. Commun. 2020, 56, 7471–7474.
    3. DOI: 10.1039/D0CC02619K
  48. Generation of Alkyl Radical through Direct Excitation of Boracene-Based Alkylborate
    1. Sato, Y.; Nakamura, K.; Sumida, Y.; Hashizume, D.; Hosoya, T.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2020, 142, 9938–9943.
    3. DOI: 10.1021/jacs.0c04456
    4. Most Read Articles (1 month)
    6. Kanazawa univ. press release　EurekAlert!　Asian Research News　Chem-Station　Nature Index
  49. Tertiary Alkylations of Aldehydes, Ketones or Imines Using Benzylic Organoboronates and a Base Catalyst
    1. Sato, Y.; Nakamura, K.; Yabushita, K.; Nagao, K.; Ohmiya, H.
    2. Bull. Chem. Soc. Jpn. 2020, 93, 1065–1069.
    3. DOI: 10.1246/bcsj.20200122
  50. N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Synthesis of δ-Ketocarbonyls
    1. Ota, K; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2020, 22, 3922–3925.
    3. DOI: 10.1021/acs.orglett.0c01199
    4. Most Read Articles (1 month)
    6. Highlighted in Synfacts
  51. Aliphatic Oxaboroles Enabling Remarkable Recognition of Diol
    1. Arakawa, N.; Nagao, K.; Murakami, R.; Sumida, Y.; Arakawa, H.; Inagaki, F.; Ohmiya, H.
    2. Bull. Chem. Soc. Jpn. 2020​, 93, 576–580 (Selected Paper).
    3. DOI: 10.1246/bcsj.20200007
  52. Allylic Cross-Coupling Using Aromatic Aldehydes as α-Alkoxyalkyl Anions
    1. Yuasa, A; Nagao, K.; Ohmiya, H.
    2. Beilstein J. Org. Chem. 2020, 16, 185–189 (Thematic issue “Copper-catalyzed reactions for organic synthesis”).
    3. DOI: 10.3762/bjoc.16.21
  53. Copper-Catalyzed Enantioselective Reductive Cross-Coupling of Aldehydes and Imines
    1. Mitsui, A.; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2020, 22, 800–803.
    3. DOI: 10.1021/acs.orglett.9b04144
  54. Organophotoredox-Catalyzed Decarboxylative C(sp3)–O Bond Formation
    1. Shibutani, S.; Kodo, T.; Takeda, M.; Nagao, K.; Tokunaga, N.; Sasaki, Y.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2020, 142, 1211–1216.
    3. DOI: 10.1021/jacs.9b12335
    4. Most Read Articles (1 month and 12 month)
    6. Highlighted in Synfacts
  55. N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes
    1. Ishii, T.; Ota, K.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2019, 141, 14073–14077.
    3. DOI: 10.1021/jacs.9b07194
    4. Most Read Articles (1 month)
    6. Kanazawa univ. press release　EurekAlert!　Highlighted in Synfacts
  56. Synergistic N-Heterocyclic Carbene/Palladium Catalyzed Aldehyde Acylation of Allylic Amines
    1. Ohnishi, N.; Yasuda, S.; Nagao, K.; Ohmiya, H.
    2. Asian. J. Org. Chem. 2019, 8, 1133–1135 (Special Issue: Heterocyclic Chemistry).
    3. DOI: 10.1002/ajoc.201900303
    4. Top Downloaded Paper 2018–2019
  57. Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand
    1. Imai, K.; Takayama, H.; Murayama, H.; Ohmiya, H.; Shimizu Y.; Sawamura, M.
    2. Org. Lett. 2019, 21, 1717–1721.
    3. DOI: 10.1021/acs.orglett.9b00276
  58. N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes
    1. Ishii, T.; Kakeno, Y.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2019, 141, 3854–3858.
    3. DOI: 10.1021/jacs.9b00880
    4. Most Read Articles (1 month and 12 month)
    6. Kanazawa univ. press release　Highlighted in ChemistryViews　EurekAlert!　Highlighted in Synfacts
    7. Highlighted in Angew. Chem. Int. Ed.
  59. Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Allylation of Aldehydes with Allylic Carbonates
    1. Takemoto, S.; Ishii, T.; Yasuda, S.; Ohmiya, H.
    2. Bull. Chem Soc. Jpn. 2019, 92, 937–940 (Selected Paper).
    3. DOI: 10.1246/bcsj.20190012
  60. Reductive Coupling between Aromatic Aldehydes and Ketones or Imines by Copper Catalysis
    1. Takeda, M.; Mitsui, A.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2019, 141, 3664–3669 (Supplementary Cover ).
    3. DOI: 10.1021/jacs.8b13309
    4. Most Read Articles (1 month)
    6. Kanazawa univ. press release　EurekAlert!　Chem-Station
  61. Asymmetric Catalysis Using Aromatic Aldehydes as Chiral α-Alkoxyalkyl Anions
    1. Yabushita, K.; Yuasa, A.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2019, 141, 113–117.
    3. DOI: 10.1021/jacs.8b11495
    4. Most Read Articles (1 month)
    6. Kanazawa univ. press release　EurekAlert!
  62. Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis
    1. Haruki, H.; Yasuda, S.; Nagao, K.; Ohmiya, H.
    2. Chem. Eur. J. 2019, 25, 724–727 (Front Cover , Cover Profile ).
    3. DOI: 10.1002/chem.201805955
    4. Top Downloaded Paper 2018–2019
    6. EurekAlert!
  63. Synergistic Palladium/Copper-Catalyzed Csp3–Csp2 Cross-Couplings Using Aldehydes As Latent α-Alkoxyalkyl Anion Equivalents.
    1. Takeda, M.; Yabushita, K.; Yasuda, S.; Ohmiya, H.
    2. Chem. Commun. 2018, 54, 6776–6779 (Back Cover, Emerging Investigators 2018 Issue).
    3. DOI: 10.1039/c8cc01055b
  64. Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Reactions of Aldehyde Acyl Anions with either Diarylmethyl or Allylic Carbonates.
    1. Yasuda, S.; Ishii, T.; Takemoto, S.; Haruki, H.; Ohmiya, H.
    2. Angew. Chem. Int. Ed. 2018, 57, 2938–2942.
    3. DOI: 10.1002/anie.201712811
    5. Kanazawa univ. press release　EurekAlert! 　Chem-Station
  65. Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes
    1. Nagao, K.; Yamazaki, A.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2018, 20, 1861–1865.
    3. DOI: 10.1021/acs.orglett.8b00390
  66. Enantiocontrol by Assembled Attractive Interactions in Copper-catalyzed Asymmetric Direct Alkynylation of  α-Ketoesters with Terminal Alkynes: OH···O/sp3-CH···O Two-point Hydrogen-bonding Combined with Dispersive Attractions
    1. Schwarzer, M. C.; Fujioka, A.; Ishii, T.; Ohmiya, H.; Mori, S.; Sawamura, M.
    2. Chem. Sci. 2018, 9, 3484–3493.
    3. DOI: 10.1039/C8SC00527C
  67. Copper-Catalyzed Enantioselective Intramolecular Alkylboron Allylic Alkylation
    1. Hojoh, K.; Shido, Y.; Ohmiya, H.; Sawamura, M.
    2. Chem. Lett. 2018, 47, 632–635..
    3. DOI: 10.1246/cl.180147
  68. Copper-Catalyzed Enantioselective Coupling between Allylboronates and Phosphates Using a Phenol-Carbene Chiral Ligand: Asymmetric Synthesis of Chiral Branched 1,5-Dienes
    1. Yasuda, Y.; Ohmiya, H.; Sawamura, M.
    2. Synthesis 2018, 50, 2235–2246.
    3. DOI: 10.1055/s-0036-1591548
  69. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multi-Substituted γ-Borylallylboranes
    1. Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2018, 57, 3196–3199.
    3. DOI: 10.1002/anie.201712351
  70. Asymmetric Synthesis of β-Lactams through Copper-Catalyzed Alkyne–Nitrone Coupling with a Prolinol-Phosphine Chiral Ligand.
    1. Takayama, Y.; Ishii, T.; Ohmiya, H.; Iwai, T.; Schwarzer, M. C.; Mori, S.; Taniguchi, T.; Monde, K.; Sawamura, M.
    2. Chem. Eur. J. 2017, 23, 8400–8404.
    3. DOI: 10.1002/chem.201702070
  71. Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides
    1. Hojoh, K.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2017, 139, 2184-2187.
    3. DOI: 10.1021/jacs.6b12881
  72. Copper-Catalyzed Enantioselective Allyl-Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand
    1. Yasuda, Y.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2016 , 55, 10816–10820.
    2. DOI: 10.1002/anie.201605125
  73. Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates
    1. Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2016, 18, 1706–1709.
    3. DOI: 10.1021/acs.orglett.6b00677
  74. Copper-Catalyzed Semihydrogenation of Internal Alkynes with Molecular Hydrogen
    1. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Organometallics 2016, 35, 1354–1357.
    3. DOI: 10.1021/acs.organomet.6b00126
  75. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles
    1. Ohmiya, H.; Zhang, H.; Shibata, S.; Harada, A.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2016, 55, 4777–4780.
    3. DOI: 10.1002/anie.201600619
  76. Copper-Catalyzed Stereoselective Conjugate Addition of Alkylboranes to Alkynoates.
    1. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Beilstein J. Org. Chem. 2015, 11, 2444–2450.
    3. DOI: 10.3762/bjoc.11.265
  77. Silica-supported Triptycene-type Phosphine. Synthesis, Characterization, and Application to Pd-Catalyzed Suzuki-Miyaura Cross-coupling of Chloroarenes.
    1. Iwai, T.; Konishi, S.; Miyazaki, T.; Kawamorita, S.; Yokokawa, N.; Ohmiya, H.; Sawamura, M.
    2. ACS Catal. 2015, 5, 7254–7264.
    3. DOI: 10.1021/acscatal.5b00904
  78. Synthesis of 1,1-Diborylalkenes through a Bronsted-base-catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron.
    1. Morinaga, A.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2015, 54, 15859–15862.
    3. DOI: 10.1002/anie.201509218
  79. Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes.
    1. Hojoh, K.; Shido, Y.; Nagao, K.; Mori, S.; Ohmiya, H.; Sawamura, M.
    2. Tetrahedron 2015, 71, 6519–6533.
    3. DOI: 10.1016/j.tet.2015.05.048
  80. Copper-Catalyzed γ-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes.
    1. Yasuda, Y.; Nagao, K.; Shido, Y.; Mori, S.; Ohmiya, H.; Sawamura, M.
    2. Chem. Eur. J. 2015, 21, 9666–9670.
    3. DOI: 10.1002/chem.201501055
  81. Copper(I)-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Alkenes.
    1. Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2015, 17, 2039–2041.
    3. DOI: 10.1021/acs.orglet.5b00758
  82. Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis.
    1. Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2015, 17, 1304–1307.
    3. DOI: 10.1021/acs.orglett.5b00305
  83. Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles.
    1. Harada, A.; Makida, Y.; Sato, T.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2014, 136, 13932–13939.
    3. DOI: 10.1021/ja5084333
  84. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes.
    1. Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2014, 136, 10605–10608.
    3. DOI: 10.1021/ja506310v
  85. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes.
    1. Hojoh, K.; Shido,Y.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2014, 53, 4954–4958 (Hot Paper).
    3. DOI: 10.1002/anie.201402386
  86. Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling with Alkylboranes, Alkynoates, and Tributyltin Methoxide.
    1. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2013, 52, 11620–11623.
    3. DOI: 10.1002/anie.201305973
  87. Cooperative Catalysis of Metal and O-H・・・O/sp3-C-H・・・O Two-point Hydrogen Bonds in Alcoholic Solvents: Copper-catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes.
    1. Ishii, T.; Watanabe, R.; Moriya, T.; Ohmiya, H,; Mori, S.; Sawamura, M.
    2. Chem. Eur. J. 2013, 19, 13547–13553.
    3. DOI: 10.1002/chem.201301280
  88. Copper-Catalyzed γ-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes.
    1. Makida, Y.; Takayama, Y.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2013, 52, 5350–5354.
    3. DOI: 10.1002/anie.201300785
  89. Use of a Semihollow-Shaped Triethynylphosphane Ligand for Efficient Formation of Six- and Seven-Membered Ring Ethers through Gold(I)-Catalyzed Cyclization of Hydroxy-Tethered Propargylic Esters.
    1. Ito, H.; Harada, A.; Ohmiya, H.; Sawamura, M.
    2. Adv. Synth. Catal. 2013, 355, 647–652.
    3. DOI: 10.1002/adsc.201200949
  90. Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes.
    1. Shido, Y.; Yoshida M.; Tanabe, M.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2012, 134, 18573–18576.
    3. DOI: 10.1021/ja3093955
  91. Conjugate Reduction of α,β-Unsaturated Carbonyl and Carboxyl Compounds with Poly(methylhydrosiloxane) Catalyzed by a Silica-Supported Compact Phosphane-Copper Complex.
    1. Kawamorita, S.; Yamazaki, K.; Ohmiya, H.; Iwai, T.; Sawamura, M. Adv. Synth. Catal. 2012, 354, 3440–3444.
    2. DOI: 10.1002/adsc.201200555
  92. Rh-Catalyzed Borylation of N-Adjacent C(sp3)-H Bonds with a Silica-Supported Triarylphosphine Ligand.
    1. Kawamorita, S.; Miyazaki, T.; Iwai, T.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2012, 134, 12924–12927.
    3. DOI: 10.1021/ja305694r
  93. Synthesis of Allenylsilanes through Copper-Catalyzed γ-Selective Coupling between γ-Silylated Propargylic Phosphates and Alkylboranes.
    1. Yokobori, U.; Ohmiya, H.; Sawamura, M.
    2. Organometallics 2012, 31, 7909–7913.
    3. DOI: 10.1021/om300552f
  94. Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper-N-Heterocyclic Carbene Complex.
    1. Yoshida, M.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2012, 134, 11896–11899.
    3. DOI: 10.1021/ja304481a
  95. Reversible 1,3-Anti/Syn Stereochemical Courses in Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes.
    1. Nagao, K.; Yokobori, U.; Makida, Y.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2012, 134, 8982–8987.
    3. DOI: 10.1021/ja302520h
  96. Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes.
    1. Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Synthesis 2012, 44, 1535–1541.
    3. DOI: 10.1055/s-0031-1290818
  97. Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation.
    1. Makida, Y.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2012, 51, 4122–4127.
    3. DOI: 10.1002/anie.201200809
  98. Synthesis of Conjugated Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates.
    1. Yang, M.; Yokokawa, N.;Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2012, 14, 816–819.
    3. DOI: 10.1021/ol2033465
  99. Efficient Preparation of β-Branched γ,δ -Unsaturated Esters through Copper-Catalyzed Allylic Alkylation of Ketene Silyl Acetal.
    1. Li, D.; Ohmiya, H.; Sawamura, M. Synthesis 2012, 44, 1304–1307.
    2. DOI: 10.1055/s-0031-1289712
  100. Rh-Catalyzed Ortho-Selective C-H Borylation of N-Functionalized Arenes with Silica-Supported Bridgehead Monophosphine Ligands.
    1. Kawamorita, S.; Miyazaki, T.; Ohmiya, H.; Iwai, T.; Sawamura, M.
    2. J. Am. Chem. Soc. 2011, 133, 19310–19313.
    3. DOI: 10.1021/ja208364a
  101. General Approach to Allenes through Copper-Catalyzed gannma γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Alkylboranes.
    1. Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M.
    2. Org. Lett. 2011, 13, 6312–6315.
    3. DOI: 10.1021/ol202866h
  102. Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with Silica-Supported Compact Phosphane Ligand.
    1. Kawamorita, S.; Ohmiya, H.; Iwai, T.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2011, 50, 8363–8366 (VIP).
    3. DOI: 10.1002/anie.201103224
  103. Intramolecular Hydroamination of Alkynic Sulfonamides Catalyzed by Gold-Triethynylphosphine Complex: Construction of Azepine Frameworks by 7-Exo-dig Cyclization.
    1. Ito, H.; Harada, T.; Ohmiya, H.; Sawamura, M.
    2. Beilstein. J. Org. Chem. 2011, 7, 951–959.
    3. DOI: 10.3762/bjoc.7.106
  104. Copper-Catalyzed Conjugate Additions of Alkylboranes to Aryl α,β-Unsaturated Ketones.
    1. Ohmiya, H.; Shido, Y.; Yoshida, M.; Sawamura, M.
    2. Chem. Lett. 2011, 40, 928–930.
    3. DOI: 10.1246/cl.2011.928
  105. Copper-Catalyzed γ-Selective and Stereospecific Allylic Alkylation of Ketene Silyl Acetals.
    1. Li, D.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2011, 133, 5672–5675.
    3. DOI: 10.1021/ja111645q
  106. Copper-Catalyzed Carboxylation of Alkylboranes with Carbon Dioxide: Formal Reductive Carboxylation of Terminal Alkenes.
    1. Ohmiya, H.; Tanabe, M.; Sawamura, M.
    2. Org. Lett. 2011, 13, 1086–1088.
    3. DOI: 10.1021/ol103128x
  107. Copper-Catalyzed Conjugate Additions of Alkylboranes to Imidazolyl α,β-Unsaturated Ketones: Formal Reductive Conjugate Addition of Terminal Alkenes.
    1. Ohmiya, H.; Yoshida, M.; Sawamura, M.
    2. Org. Lett. 2011, 13, 482–485.
    3. DOI: 10.1021/ol102819k
  108. Sulfonamidoquinoline-Palladium(II) Dimer Complex As a Catalyst Precursor for Palladium-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling Reaction between Allylic Acetates and Arylboronic Acids.
    1. Makida, Y.; Ohmiya, H.; Sawamura, M.
    2. Chem. Asian J. 2011, 6, 410–414.
    3. DOI: 10.1002/asia.201000721
  109. Construction of Methylenecycloheptane Frameworks through 7-Exo-dig Cyclization of Acetylenic Silyl Enol Ethers Catalyzed by Triethynylphosphine-Gold Complex.
    1. Ito, H.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2010, 12, 4380–4383.
    3. DOI: 10.1021/ol101860j
  110. Directed Ortho Borylation of Phenol Derivatives Catalyzed by a Silica-Supported Iridium Complex.
    1. Yamazaki, K.; Kawamorita, S.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2010, 12, 3978–3981.
    3. DOI: 10.1021/ol101493m
  111. Protecting-Group-Free Route to Hydroxylated Pyrrolidine and Piperidine Derivatives through Cu(I)-Catalyzed Intramolecular Hydroamination of Alkenes.
    1. Ohmiya, H.; Yoshida, M.; Sawamura, M.
    2. Synlett 2010, 2136–2140.
    3. DOI: 10.1055/s-0030-1258527
  112. Synthesis of α-Arylated Allylsilanes through Palladium-Catalyzed γ-Selective Allyl-Aryl Coupling.
    1. Li, D.; Tanaka, T.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2010, 12, 3344–3347.
    3. DOI: 10.1021/ol101114r
  113. Copper-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling between (Z)-Acyclic and Cyclic Allylic Phosphates and Arylboronates.
    1. Ohmiya, H.; Yokokawa, N.; Sawamura, M.
    2. Org. Lett. 2010, 12, 2438–2440.
    3. DOI: 10.1021/ol100841y
  114. Ester-Directed Regioselective Borylation of Heteroarenes Catalyzed by a Silica-Supported Iridium Complex.
    1. Kawamorita, S.; Ohmiya, H.; Sawamura, M.
    2. J. Org. Chem. 2010, 75, 3855–3858.
    3. DOI: 10.1021/jo100352b
  115. Selective Synthesis of Allenes and Alkynes through Ligand-Controlled, Palladium-Catalyzed Decarboxylative Hydrogenolysis of Propargylic Formates.
    1. Ohmiya, H.; Yang, M.; Yamauchi, Y.; Ohtsuka, Y.; Sawamura, M.
    2. Org. Lett. 2010, 12, 1796–1799.
    3. DOI: 10.1021/ol100405k
  116. Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes.
    1. Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M.
    2. J. Am. Chem. Soc. 2010, 132, 2895–2897.
    3. DOI: 10.1021/ja9109105
  117. Palladium-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling between Acyclic Allylic Esters and Arylboronic Acids.
    1. Ohmiya, H.; Makida, Y.; Li, D.; Tanabe, M.; Sawamura, M.
    2. J. Am. Chem. Soc. 2010, 132, 879–889.
    3. DOI: 10.1021/ja9092264
  118. General and Functional Group-Tolerable Approach to Allenylsilanes by Rhodium-Catalyzed Coupling between Propargylic Carbonates and a Silylboronate.
    1. Ohmiya, H.; Ito, H.; Sawamura, M.
    2. Org. Lett. 2009, 11, 5618–5620.
    3. DOI: 10.1021/ol902339a
  119. Cu(I)-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes Bearing a Primary or Secondary Amino Group in Alcoholic Solvents.
    1. Ohmiya, H.; Moriya, T.; Sawamura, M.
    2. Org. Lett. 2009, 11, 2145–2147.
    3. DOI: 10.1021/ol9007712
  120. Directed ortho-Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine-Iridium System.
    1. Kawamorita, S.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M.
    2. J. Am. Chem. Soc. 2009, 131, 5058–5059.
    3. DOI: 10.1021/ja9008419
  121. Palladium-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling between Allylic Acetates and Arylboronic Acids.
    1. Ohmiya, H.; Makida, Y.; Tanaka, T.; Sawamura, M.
    2. J. Am. Chem. Soc. 2008, 130, 17276–17277.
    3. DOI: 10.1021/ja808673n
  122. Cyclization of NonTerminal Alkynic β-Keto Esters Catalyzed by Gold(I) Complex with a Semihollow, End-Capped Triethynylphosphine Ligand.
    1. Ito, H.; Makida, Y.; Ochida, A.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2008, 10, 5051–5054.
    3. DOI: 10.1021/ol802079r
  123. Synthesis of Silica-Supported Compact Phosphines and Their Application to Rhodium-Catalyzed Hydrosilylation of Hindered Ketones with Triorganosilanes.
    1. Hamasaka, G.; Kawamorita, S.; Ochida, A.; Akiyama, R.; Hara, K.; Fukuoka, A.; Asakura, K.; Chun, W. J.; Ohmiya, H.; Sawamura, M.
    2. Organometallics 2008, 27, 6495–6506.
    3. DOI: 10.1021/om800683g
  124. Hydrogenation of Hindered Ketones Catalyzed by a Silica-Supported Compact Phosphine-Rh System.
    1. Kawamorita, S.; Hamasaka, G.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M.
    2. Org. Lett. 2008, 10, 4697–4700.
    3. DOI: 10.1021/ol801996r
  125. Synthesis, Properties and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane.
    1. Ochida, A.; Hamasaka, G.; Yamauchi, Y.; Kawamorita, S.; Oshima, N.; Hara, K.; Ohmiya, H.; Sawamura, M.
    2. Organometallics 2008, 27, 5494–5503.
    3. DOI: 10.1021/om8005728
  126. Cobalt-Catalyzed Regioselective Dehydrohalogenation of Alkyl Halides with Dimethylphenylsilylmethylmagnesium Chloride.
    1. Kobayashi, T.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. J. Am. Chem. Soc. 2008, 130, 11276–11277.
    3. DOI: 10.1021/ja804277x
  127. Silver-Catalyzed Benzylation and Allylation Reactions of Tertiary and Secondary Alkyl Halides with Grignard Reagents.
    1. Someya, H.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Org. Lett. 2008, 10, 969–971.
    3. DOI: 10.1021/ol800038a
  128. Generation of Rhodium Enolates via Retro-Aldol Reaction and Its Application to Regioselective Aldol Reaction.
    1. Murakami, K.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Tetrahedron Lett. 2008, 49, 2388–2390.
    3. DOI: 10.1016/j.tetlet.2008.02.062
  129. Alpha Olefins as Alkenylmetal Equivalents in Catalytic Conjugate Addition Reactions.
    1. Ho, C.-Y.; Ohmiya, H.; Jamison, T. F.
    2. Angew. Chem. Int. Ed. 2008, 47, 1893–1895.
    3. DOI: 10.1002/anie.200705163
  130. N-Heterocyclic Carbene Ligands in Cobalt-Catalyzed Sequential Cyclization/Cross-Coupling Reactions of 6-Halo-1-hexene Derivatives with Grignard Reagents.
    1. Someya, H.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Org. Lett. 2007, 9, 1565–1567.
    3. DOI: 10.1021/ol070392f
  131. Cobalt-Catalyzed Sequential Cyclization/Cross-Coupling Reactions of 6-Halo-1-hexene Derivatives with Grignard Reagents and Their Application to the Synthesis of 1,3-Diols.
    1. Someya, H.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Tetrahedron 2007, 63, 8609–8618.
    3. DOI: 10.1016/j.tet.2007.04.083
  132. Chromium-Catalyzed Arylmagnesiation of Alkynes.
    1. Murakami, K.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Org. Lett. 2007, 9, 1569–1571.
    3. DOI: 10.1021/ol0703938
  133. Nickel-Catalyzed Carbometalation Reactions of [2-(1-Propynyl)phenyl]methanol with 1-Alkenylmagnesium Reagents.
    1. Murakami, K.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Chem. Lett. 2007, 36, 1066–1067.
    3. DOI: 10.1246/cl.2007.1066
  134. A New Approach to 4-Aryl-1,3-butanediols by Cobalt-Catalyzed Sequential Radical Cyclization/Arylation Reaction of Silicon-tethered 6-Iodo-1-hexene Derivatives.
    1. Someya, H.; Kondoh, A.; Sato, A.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Synlett 2006, 18, 3061–3064.
    3. DOI: 10.1055/s-2006-951508
  135. Cobalt(diamine)-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Arylmagnesium Reagents: Stereoselective Constructions of Arylated Asymmetric Carbons and Application to Total Synthesis of AH13205.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. J. Am. Chem. Soc. 2006, 128, 1886–1889.
    3. DOI: 10.1021/ja057560o
  136. Cobalt-Mediated Cross-Coupling Reactions of Primary and Secondary Alkyl Halides with 1-(Trimethylsilyl)ethenyl- and 2-Trimethylsilylethynylmagnesium Reagents.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Org. Lett. 2006, 8, 3093–3096.
    3. DOI: 10.1021/ol0611144
  137. Cobalt-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Aryl Grignard Reagents and Their Application to Sequential Radical Cyclization/Cross-Coupling Reactions.
    1. Ohmiya, H.; Wakabayashi, K.; Yorimitsu, H.; Oshima, K.
    2. Tetrahedron 2006, 62, 2207–2213.
    3. DOI: 10.1016/j.tet.2005.12.013
  138. Cobalt-Catalyzed Trimethylsilylmethylmagnesium-Promoted Radical Alkenylation of Alkyl Halides: A Complement to the Heck Reaction.
    1. Affo, W.; Ohmiya, H.; Fujioka, T.; Ikeda, Y.; Nakamura, T.; Yorimitsu, H.; Oshima, K.; Imamura, Y.; Mizuta, T.; Miyoshi, K.
    2. J. Am. Chem. Soc. 2006, 128, 8068–8077.
    3. DOI: 10.1021/ja061417t
  139. Cobalt-Catalyzed Syn-Hydrophosphination of Alkynes.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Angew. Chem. Int. Ed. 2005, 44, 2368–2370.
    3. DOI: 10.1002/anie.200500255
  140. Regio- and Stereoselective Approach to 1,2-Di- and 1,1,2-Trisilylethenes by Cobalt-Mediated Reaction of Silyl-Substituted Dibromomethanes with Silylmethylmagnesium.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Angew. Chem. Int. Ed. 2005, 44, 3488–3490.
    3. DOI: 10.1002/anie.200500576
  141. Cobalt-Catalyzed Cross-Coupling Reaction of Chloropyridines with Grignard Reagents.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Chem. Lett. 2004, 33, 1240–1241.
    3. DOI: 10.1246/cl.2004.1240
  142. Cobalt-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Allylic and Benzylic Grignard Reagents and Their Application to Tandem Radical Cyclization/Cross-Coupling Reactions.
    1. Ohmiya, H.; Tsuji, T.; Yorimitsu, H.; Oshima, K. Chem. Eur. J. 2004, 10, 5640–5648.
    2. DOI: 10.1002/chem.200400545
  143. Novel Synthesis of 5-Thio-hexopyranoside: Preparation of 5-Thio-D- and L-glucose and 1,6-Anhydro-5-thio-L- and D-altrose.
    1. Uenishi, J. i.; Ohmiya, H.
    2. Tetrahedron 2003, 59, 7011–7022.
    3. DOI: 10.1016/S0040-4020(03)00864-0
  144. Studies on Stereoselective Sonogashira Coupling of 1,1-Dibromo-1-alkene.
    1. Uenishi, J. i.; Matsui, K.; Ohmiya, H.
    2. J. Organomet. Chem. 2002 , 653, 141–149.
          1. DOI: 10.1016/S0022-328X(02)01262-7

Others

  1. Science of Synthesis: Compounds of Group 15 (As, Sb, Bi) and Silicon Compounds: Silylmethyl Anions
    1. Sumida, Y.; Ohmiya, H
    2. Science of Synthesis, 2022/3: Knowledge Updates 2022/3
    3. DOI: 10.1055/sos-SD-104-00799
  2. Direct Excitation Strategy for Radical Generation in Organic Synthesis
    1. Sumida, Y.; Ohmiya, H.
    2. Chem. Soc. Rev. 2021, 50, 6320–6332.
    3. DOI: 10.1039/d1cs00262g
  3. N-Heterocyclic Carbene-Based Catalysis Enabling Cross-Coupling Reactions
    1. Ohmiya, H.
    2. ACS Catal. 2020, 10, 6862–6869.
    3. DOI: 10.1021/acscatal.0c01795
    4. Most Read Articles (1 month)
  4. Recent Advances in N-Heterocyclic Carbene-Based Radical Catalysis
    1. Ishii, T.; Nagao, K.; Ohmiya, H.
    2. Chem. Sci. 2020, 11, 5630–5636.
    3. DOI: 10.1039/D0SC01538E
  5. Copper-Catalyzed Reactions of Alkylboranes
    1. Ohmiya, H.; Sawamura, M.
    2. Bull. Chem. Soc. Jpn. 2020, 93, 197–203.
    3. DOI: 10.1246/bcsj.20200283
  6. N-Heterocyclic Carbene (NHC)/Metal Cooperative Catalysis
    1. Nagao, K.; Ohmiya, H. Top. Curr. Chem. 2019, 377, 35.
    2. DOI: 10.1007/s41061-019-0266-z
  7. 有機触媒で電子反応を制御する
    1. 大宮寛久
    2. ファルマシア 2020, 56, 935–937.
    3. DOI: 10.14894/faruawpsj.56.10_935
  8. Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis
    1. Sawamura, M.; Ohmiya, H
    2. Fernández, E., Ed.; Thieme: Stuttgart, (2019); p 105–130.
    3. DOI: 10.1055/sos-SD-230-00048
  9. アルデヒドをキラルα-アルコキシアルキルアニオンとして活用する不斉触媒反応
    1. 大宮寛久
    2. ファインケミカル 2019, 48, 41–44.
  10. ある若手PIの回想
    1. 大宮寛久
    2. 有機合成化学協会誌 2019, 77, 732–734.
    3. Message from Young Principal Researcher (MyPR)
  11. ヘテロ芳香環の位置選択的官能基化
    1. 長尾一哲・大宮寛久
    2. 化学 2018, 73, 66–67.
  12. Hirohisa Ohmiya’s Author Profile
    1. Angew. Chem. Int. Ed. 2018, 57, 13718
    2. DOI: 10.1002/anie.201805108
  13. アルデヒドを求核剤原料として用いる極性転換型反応
    1. 大宮寛久
    2. Organometallic News 2018, 49–52.
  14. 銅触媒の機能化に基づく高選択的合成反応の開発
    1. 大宮寛久・澤村正也
    2. 化学工業 2016, 67, 361–366 （特集: 戦略的触媒開発と応用）.
  15. 有機金属ハイライト「 1,2- メタレート転位の新展開」
    1. 大宮寛久
    2. Organometallic News 2016, 34
  16. Copper-Catalyzed Allylic Substitution and Conjugate Addition with Alkylboranes.
    1. Ohmiya, H.; Sawamura, M.
    2. J. Synth. Org. Chem. Jpn. 2014 , 72, 1207–1217 (Special Issue in English).
  17. 飛翔する若手研究者「アリル化の反応位置を究める」
    1. 大宮寛久
    2. 化学と工業 2011, 64-8, pp 627.
  18. 注目の論文「定説への挑戦」
    1. 大宮寛久
    2. 化学 2009, 64, 64–65.
  19. 海外研究室レポート「 MIT・Timothy F. Jamison 研究室」
    1. 大宮寛久
    2. Organometallic News 2009 , 85, 106–107.
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