Publication

Prof. Dr. Hirohisa Ohmiya

Original publications

  1. Light-Driven Radical-Polar Crossover Catalysis for Cross-Coupling with Organosilanes
    1. Matsuo, T.; Nagao, K.; Ohmiya, H.
    2. Tetrahedron Lett. 2022, in press (Special Issue on “Recent Advances in Photocatalysis for Selective Organic Synthesis”).
    3. https://doi.org/10.1016/j.tetlet.2022.154231
  2. Organic Photoredox-Catalyzed Silyl Radical Generation from Silylboronate
    1. Takemura, N.; Sumida, Y.; Ohmiya, H.
    2. ACS Catal. 2022, 12, 7804–7810.
    3. 10.1021/acscatal.2c01964
    4. Most Read Articles (1 month)
  3. Direct Photoexcitable Iodomethylborate Enabling Cyclopropanation of Reactive Alkenes
    1. Nakamura, R.; Sumida, Y.; Ohmiya, H.
    2. Bull. Chem. Soc. Jpn. 2022 , 95, 1001–1005 (Selected Paper).
    3. DOI: 10.1246/bcsj.20220112
  4. Organophotoredox-Catalyzed Semipinacol Rearrangement via Radical-Polar Crossover
    1. Kodo, T.; Nagao, K.; Ohmiya, H.
    2. Nat. Commun. 2022, 13, 2684.
    3. DOI: 10.1038/s41467-022-30395-4
    4. Kyoto univ., Kanazawa univ. and JST press release
  5. A Triple Photoredox/Cobalt/Bronsted Acid Catalysis Enabling Markovnikov Hydroalkoxylation of Unactivated Alkenes
    1. Nakagawa, M.; Matsuki, Y.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2022, 144, 7953–7959.
    3. DOI: 10.1021/jacs.2c00527
    4. Most Read Articles (1 month)
    5. Kyoto univ. and Kanazawa univ. press release   EurekAlert!
  6. Reductive Cross-Coupling between Arylaldehydes and (Hetero)aryl Electrophiles Using Silylboronate Reductant
    1. Watanabe, K.; Takeda, M.; Nagao, K.; Ohmiya, H.
    2. Eur. J. Org. Chem. 2022, e202200005 (Virtual Special Collection on “Silicon Chemistry in Organic Synthesis”).
    3. DOI: 10.1002/ejoc.202200005
  7. Molecular Field Analysis Using Computational-Screening Data in Asymmetric N-Heterocyclic Carbene-Copper Catalysis toward Data-driven in silico Catalyst Optimization
    1. Mukai, M.; Nagao, K.; Yamaguchi, S.; Ohmiya, H.
    2. Bull. Chem. Soc. Jpn. 2022 , 95, 271–277 (Selected Paper).
    3. DOI: 10.1246/bcsj.20210349
    4. Riken and Kanazawa univ. press release
  8. Direct Photoexcitation of Borate Enabling Minisci Reaction
    1. Kemmochi, M.; Miyamoto, Y.; Sumida, Y.; Ohmiya, H.
    2. Asian. J. Org. Chem. 2022, 11, e2021006 (AsianJOCs 10th Anniversary Special Collection).
    3. DOI: 10.1002/ajoc.202100640
  9. Light-Driven N-Heterocyclic Carbene Catalysis Using Alkylborates
    1. Sato, Y.; Goto, Y.; Nakamura, K.; Miyamoto, Y.; Sumida, Y.; Ohmiya, H.
    2. ACS Catal. 2021, 11, 12886–12892.
    3. DOI: 10.1021/acscatal.1c04153
    4. Most Read Articles (1 month)
  10. Radical Relay Trichloromethylacylation of Alkenes through N-Heterocyclic Carbene Catalysis
    1. Kusakabe, M.; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 7242–7247.
    3. DOI: 10.1021/acs.orglett.1c02639
  11. Organophotoredox-Catalyzed Decarboxylative N-Alkylation of Sulfonamides
    1. Nakagawa, M.; Nagao, K.; Ikeda, Z.; Reynolds, M.; Ibáñez, I.; Wang, J.; Tokunaga, N.; Sasaki, Y.; Ohmiya, H.
    2. ChemCatChem 2021, 13, 3930–3933 (part of a joint Special Collection with EurJIC on “Main Group Catalysis”)
    3. DOI: 10.1002/cctc.202100803
  12. Generation of Functionalized Alkyl Radicals via the Direct Photo-Excitation of PDP-Based Borates
    1. Miyamoto, Y.; Sumida, Y.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 5865–5870.
    3. DOI: 10.1021/acs.orglett.1c01996
    4. Most Read Articles (1 month)
  13. Aryl Radical-Mediated N-Heterocyclic Carbene Catalysis
    1. Matsuki, Y.; Ohnishi, N.; Kakeno, Y.; Takemoto, S.; Ishii, T.; Nagao, K.; Ohmiya, H.
    2. Nat. Commun. 2021, 12, 3848.
    3. DOI: 10.1038/s41467-021-24144-2
    4. Kanazawa univ. and JST press release   EurekAlert! Asian Research News Science Japan
  14. Decarboxylative N-Alkylation of Azoles Through Visible-Light-Mediated Organophotoredox Catalysis
    1. Kobayashi, R.; Shibutani, S.; Nagao, K.; Ikeda, Z.; Wang, J.; Ibáñez, I.; Reynolds, M.; Sasaki, Y.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 5415–5419 (Supplementary Cover ).
    3. DOI: 10.1021/acs.orglett.1c01745
    4. Most Read Articles (1 month)
  15. Synthesis of Sterically Hindered α-Hydroxycarbonyls through Radical–Radical Coupling
    1. Ota, K.; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 4420–4425.
    3. DOI: 10.1021/acs.orglett.1c01358
    4. Most Read Articles (1 month)
  16. Radical N-Heterocyclic Carbene Catalysis for β-Ketocarbonyl Synthesis
    1. Ishii, T.; Nagao, K.; Ohmiya, H.
    2. Tetrahedron 2021, 91, 132212 (Special Issue on System-Oriented Development of Organocatalysis).
    3. DOI: 10.1016/j.tet.2021.132212
  17. Fluorescent-oxaboroles: Synthesis and Optical Property by Sugar Recognition
    1. Nakano, M.; Nakamura, R.; Sumida, Y.; Nagao, K.; Furuyama, T.; Inagaki, F.; Ohmiya, H.
    2. Chem. Pharm. Bull. 2021, 69, 526–528 (Featured Article).
    3. DOI: 10.1248/cpb.c21-00179
    4. Most viewed articles Jun.2021
  18. Direct Excitation Strategy for Radical Generation in Organic Synthesis
    1. Sumida, Y.; Ohmiya, H.
    2. Chem. Soc. Rev. 2021, 50, 6320–6332.
    3. DOI: 10.1039/d1cs00262g
  19. Catalytic Reductive Cross-Coupling between Aromatic Aldehydes and Arylnitriles
    1. Mitsui, A.; Nagao, K.; Ohmiya, H.
    2. Chem. Eur. J. 2021, 27, 7094–7098.
    3. DOI: 10.1002/chem.202100763
  20. Organophotoredox-Catalyzed Three-Component Coupling of Heteroatom Nucleophiles, Alkenes, and Aliphatic Redox Active Esters
    1. Shibutani, S.; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 1798-1803.
    3. DOI: 10.1021/acs.orglett.1c00211
    4. Most Read Articles (1 month)
  21. Copper-Catalyzed Reactions of Alkylboranes
    1. Ohmiya, H.; Sawamura, M.
    2. Bull. Chem. Soc. Jpn. 2020, 93, 197–203.
    3. DOI: 10.1246/bcsj.20200283
  22. Transition-Metal-Free Cross-Coupling Using Tertiary Benzylic Organoboronates
    1. Takeda, M.; Nagao, K.; Ohmiya, H.
    2. Angew. Chem. Int. Ed. 2020, 59, 22460–22464.
    3. DOI: 10.1002/anie.202010251
    4. EurekAlert!
  23. Boracene-Based Alkylborate Enabling Ni/Ir Hybrid Catalysis
    1. Sato, Y.; Miyamoto, Y.; Sumida, Y.; Hosoya, T.; Ohmiya, H.
    2. Org. Biomol. Chem. 2020, 18, 6598–6601 (Themed Issue on Hybrid Catalysis).
    3. DOI: 10.1039/D0OB01610A
  24. Direct Synthesis of Dialkyl Ketones from Aliphatic Aldehydes through Radical N-Heterocyclic Carbene Catalysis
    1. Kakeno, Y.; Kusakabe, M.; Nagao, K.; Ohmiya, H.
    2. ACS Catal. 2020, 10, 8524–8529.
    3. DOI: 10.1021/acscatal.0c02849
    4. Most Read Articles (1 month)
    5. Kanazawa univ. and JST press release   EurekAlert! Asian Research News
  25. Reductive Umpolung for Asymmetric Synthesis of Chiral α-Allenic Alcohols
    1. Kondo, Y.; Nagao, K.; Ohmiya, H.
    2. Chem. Commun. 2020, 56, 7471–7474.
    3. DOI: 10.1039/D0CC02619K
  26. N-Heterocyclic Carbene-Based Catalysis Enabling Cross-Coupling Reactions
    1. Ohmiya, H.
    2. ACS Catal. 2020, 10, 6862–6869.
    3. DOI: 10.1021/acscatal.0c01795
    4. Most Read Articles (1 month)
  27. Generation of Alkyl Radical through Direct Excitation of Boracene-Based Alkylborate
    1. Sato, Y.; Nakamura, K.; Sumida, Y.; Hashizume, D.; Hosoya, T.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2020, 142, 9938–9943.
    3. DOI: 10.1021/jacs.0c04456
    4. Most Read Articles (1 month)
    5. Kanazawa univ. press release EurekAlert! Asian Research News Chem-Station Nature Index
  28. Recent Advances in N-Heterocyclic Carbene-Based Radical Catalysis
    1. Ishii, T.; Nagao, K.; Ohmiya, H.
    2. Chem. Sci. 2020, 11, 5630–5636.
    3. DOI: 10.1039/D0SC01538E
  29. Tertiary Alkylations of Aldehydes, Ketones or Imines Using Benzylic Organoboronates and a Base Catalyst
    1. Sato, Y.; Nakamura, K.; Yabushita, K.; Nagao, K.; Ohmiya, H.
    2. Bull. Chem. Soc. Jpn. 2020, 93, 1065–1069.
    3. DOI: 10.1246/bcsj.20200122
  30. N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Synthesis of δ-Ketocarbonyls
    1. Ota, K; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2020, 22, 3922–3925.
    3. DOI: 10.1021/acs.orglett.0c01199
    4. Most Read Articles (1 month)
    5. Highlighted in Synfacts
  31. Aliphatic Oxaboroles Enabling Remarkable Recognition of Diol
    1. Arakawa, N.; Nagao, K.; Murakami, R.; Sumida, Y.; Arakawa, H.; Inagaki, F.; Ohmiya, H.
    2. Bull. Chem. Soc. Jpn. 2020​, 93, 576–580 (Selected Paper).
    3. DOI: 10.1246/bcsj.20200007
  32. Allylic Cross-Coupling Using Aromatic Aldehydes as α-Alkoxyalkyl Anions
    1. Yuasa, A; Nagao, K.; Ohmiya, H.
    2. Beilstein J. Org. Chem. 2020, 16, 185–189 (Thematic issue “Copper-catalyzed reactions for organic synthesis”).
    3. DOI: 10.3762/bjoc.16.21
  33. Copper-Catalyzed Enantioselective Reductive Cross-Coupling of Aldehydes and Imines
    1. Mitsui, A.; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2020, 22, 800–803.
    3. DOI: 10.1021/acs.orglett.9b04144
  34. Organophotoredox-Catalyzed Decarboxylative C(sp3)–O Bond Formation
    1. Shibutani, S.; Kodo, T.; Takeda, M.; Nagao, K.; Tokunaga, N.; Sasaki, Y.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2020, 142, 1211–1216.
    3. DOI: 10.1021/jacs.9b12335
    4. Most Read Articles (1 month and 12 month)
    5. Highlighted in Synfacts
  35. N-Heterocyclic Carbene (NHC)/Metal Cooperative Catalysis
    1. Nagao, K.; Ohmiya, H. Top. Curr. Chem. 2019, 377, 35.
    2. DOI: 10.1007/s41061-019-0266-z
  36. N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes
    1. Ishii, T.; Ota, K.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2019, 141, 14073–14077.
    3. DOI: 10.1021/jacs.9b07194
    4. Most Read Articles (1 month)
    5. Kanazawa univ. press release EurekAlert! Highlighted in Synfacts
  37. Synergistic N-Heterocyclic Carbene/Palladium Catalyzed Aldehyde Acylation of Allylic Amines
    1. Ohnishi, N.; Yasuda, S.; Nagao, K.; Ohmiya, H.
    2. Asian. J. Org. Chem. 2019, 8, 1133–1135 (Special Issue: Heterocyclic Chemistry).
    3. DOI: 10.1002/ajoc.201900303
    4. Top Downloaded Paper 2018–2019
  38. Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand
    1. Imai, K.; Takayama, H.; Murayama, H.; Ohmiya, H.; Shimizu Y.; Sawamura, M.
    2. Org. Lett. 2019, 21, 1717–1721.
    3. DOI: 10.1021/acs.orglett.9b00276
  39. N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes
    1. Ishii, T.; Kakeno, Y.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2019, 141, 3854–3858.
    3. DOI: 10.1021/jacs.9b00880
    4. Most Read Articles (1 month and 12 month)
    5. Kanazawa univ. press release Highlighted in ChemistryViews EurekAlert! Highlighted in Synfacts
    6. Highlighted in Angew. Chem. Int. Ed.
  40. Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Allylation of Aldehydes with Allylic Carbonates
    1. Takemoto, S.; Ishii, T.; Yasuda, S.; Ohmiya, H.
    2. Bull. Chem Soc. Jpn. 2019, 92, 937–940 (Selected Paper).
    3. DOI: 10.1246/bcsj.20190012
  41. Reductive Coupling between Aromatic Aldehydes and Ketones or Imines by Copper Catalysis
    1. Takeda, M.; Mitsui, A.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2019, 141, 3664–3669 (Supplementary Cover ).
    3. DOI: 10.1021/jacs.8b13309
    4. Most Read Articles (1 month)
    5. Kanazawa univ. press release EurekAlert! Chem-Station
  42. Asymmetric Catalysis Using Aromatic Aldehydes as Chiral α-Alkoxyalkyl Anions
    1. Yabushita, K.; Yuasa, A.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2019, 141, 113–117.
    3. DOI: 10.1021/jacs.8b11495
    4. Most Read Articles (1 month)
    5. Kanazawa univ. press release EurekAlert!
  43. Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis
    1. Haruki, H.; Yasuda, S.; Nagao, K.; Ohmiya, H.
    2. Chem. Eur. J. 2019, 25, 724–727 (Front Cover , Cover Profile ).
    3. DOI: 10.1002/chem.201805955
    4. Top Downloaded Paper 2018–2019
    5. EurekAlert!
  44. Synergistic Palladium/Copper-Catalyzed Csp3–Csp2 Cross-Couplings Using Aldehydes As Latent α-Alkoxyalkyl Anion Equivalents.
    1. Takeda, M.; Yabushita, K.; Yasuda, S.; Ohmiya, H.
    2. Chem. Commun. 2018, 54, 6776–6779 (Back Cover, Emerging Investigators 2018 Issue).
    3. DOI: 10.1039/c8cc01055b
  45. Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Reactions of Aldehyde Acyl Anions with either Diarylmethyl or Allylic Carbonates.
    1. Yasuda, S.; Ishii, T.; Takemoto, S.; Haruki, H.; Ohmiya, H.
    2. Angew. Chem. Int. Ed. 2018, 57, 2938–2942.
    3. DOI: 10.1002/anie.201712811
    4. Kanazawa univ. press release EurekAlert!  Chem-Station
  46. Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes
    1. Nagao, N.; Yamazaki, A.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2018, 20, 1861–1865.
    3. DOI: 10.1021/acs.orglett.8b00390
  47. Enantiocontrol by Assembled Attractive Interactions in Copper-catalyzed Asymmetric Direct Alkynylation of  α-Ketoesters with Terminal Alkynes: OH···O/sp3-CH···O Two-point Hydrogen-bonding Combined with Dispersive Attractions
    1. Schwarzer, M. C.; Fujioka, A.; Ishii, T.; Ohmiya, H.; Mori, S.; Sawamura, M.
    2. Chem. Sci. 2018, 9, 3484–3493.
    3. DOI: 10.1039/C8SC00527C
  48. Copper-Catalyzed Enantioselective Intramolecular Alkylboron Allylic Alkylation
    1. Hojoh, K.; Shido, Y.; Ohmiya, H.; Sawamura, M.
    2. Chem. Lett. 2018, 47, 632–635..
    3. DOI: 10.1246/cl.180147
  49. Copper-Catalyzed Enantioselective Coupling between Allylboronates and Phosphates with a Phenol-Carbene Chiral Ligand: Asymmetric Synthesis of Chiral Branched 1,5-Dienes
    1. Yasuda, Y.; Ohmiya, H.; Sawamura, M.
    2. Synthesis 2018, 50, 2235–2246.
    3. DOI: 10.1055/s-0036-1591548
  50. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multi-Substituted γ-Borylallylboranes
    1. Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2018, 57, 3196–3199.
    3. DOI: 10.1002/anie.201712351
  51. Asymmetric Synthesis of β-Lactams through Copper-Catalyzed Alkyne–Nitrone Coupling with Prolinol-Phosphine Chiral Ligand.
    1. Takayama, Y.; Ishii, T.; Ohmiya, H.; Iwai, T.; Schwarzer, M. C.; Mori, S.; Taniguchi, T.; Monde, K.; Sawamura, M.
    2. Chem. Eur. J. 2017, 23, 8400–8404.
    3. DOI: 10.1002/chem.201702070
  52. Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides
    1. Hojoh, K.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2017, 139, 2184-2187.
    3. DOI: 10.1021/jacs.6b12881
  53. Copper-Catalyzed Enantioselective Allyl-Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand
    1. Yasuda, Y.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2016 , 55, 10816–10820.
    2. DOI: 10.1002/anie.201605125
  54. Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates
    1. Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2016, 18, 1706–1709.
    3. DOI: 10.1021/acs.orglett.6b00677
  55. Copper-Catalyzed Semihydrogenation of Internal Alkynes with Molecular Hydrogen
    1. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Organometallics 2016, 35, 1354–1357.
    3. DOI: 10.1021/acs.organomet.6b00126
  56. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles
    1. Ohmiya, H.; Zhang, H.; Shibata, S.; Harada, A.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2016, 55, 4777–4780.
    3. DOI: 10.1002/anie.201600619
  57. Copper-Catalyzed Stereoselective Conjugate Addition of Alkylboranes to Alkynoates.
    1. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Beilstein J. Org. Chem. 2015, 11, 2444–2450.
    3. DOI: 10.3762/bjoc.11.265
  58. Silica-supported Triptycene-type Phosphine. Synthesis, Characterization, and Application to Pd-Catalyzed Suzuki-Miyaura Cross-coupling of Chloroarenes.
    1. Iwai, T.; Konishi, S.; Miyazaki, T.; Kawamorita, S.; Yokokawa, N.; Ohmiya, H.; Sawamura, M.
    2. ACS Catal. 2015, 5, 7254–7264.
    3. DOI: 10.1021/acscatal.5b00904
  59. Synthesis of 1,1-Diborylalkenes through a Bronsted-base-catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron.
    1. Morinaga, A.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2015, 54, 15859–15862.
    3. DOI: 10.1002/anie.201509218
  60. Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes.
    1. Hojoh, K.; Shido, Y.; Nagao, K.; Mori, S.; Ohmiya, H.; Sawamura, M.
    2. Tetrahedron 2015, 71, 6519–6533.
    3. DOI: 10.1016/j.tet.2015.05.048
  61. Copper-Catalyzed γ-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes.
    1. Yasuda, Y.; Nagao, K.; Shido, Y.; Mori, S.; Ohmiya, H.; Sawamura, M.
    2. Chem. Eur. J. 2015, 21, 9666–9670.
    3. DOI: 10.1002/chem.201501055
  62. Copper(I)-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Alkenes.
    1. Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2015, 17, 2039–2041.
    3. DOI: 10.1021/acs.orglet.5b00758
  63. Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis.
    1. Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2015, 17, 1304–1307.
    3. DOI: 10.1021/acs.orglett.5b00305
  64. Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles.
    1. Harada, A.; Makida, Y.; Sato, T.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2014, 136, 13932–13939.
    3. DOI: 10.1021/ja5084333
  65. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes.
    1. Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2014, 136, 10605–10608.
    3. DOI: 10.1021/ja506310v
  66. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes.
    1. Hojoh, K.; Shido,Y.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2014, 53, 4954–4958 (Hot Paper).
    3. DOI: 10.1002/anie.201402386
  67. Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling with Alkylboranes, Alkynoates, and Tributyltin Methoxide.
    1. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2013, 52, 11620–11623.
    3. DOI: 10.1002/anie.201305973
  68. Cooperative Catalysis of Metal and O-H・・・O/sp3-C-H・・・O Two-point Hydrogen Bonds in Alcoholic Solvents: Copper-catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes.
    1. Ishii, T.; Watanabe, R.; Moriya, T.; Ohmiya, H,; Mori, S.; Sawamura, M.
    2. Chem. Eur. J. 2013, 19, 13547–13553.
    3. DOI: 10.1002/chem.201301280
  69. Copper-Catalyzed γ-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes.
    1. Makida, Y.; Takayama, Y.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2013, 52, 5350–5354.
    3. DOI: 10.1002/anie.201300785
  70. Use of a Semihollow-Shaped Triethynylphosphane Ligand for Efficient Formation of Six- and Seven-Membered Ring Ethers through Gold(I)-Catalyzed Cyclization of Hydroxy-Tethered Propargylic Esters.
    1. Ito, H.; Harada, A.; Ohmiya, H.; Sawamura, M.
    2. Adv. Synth. Catal. 2013, 355, 647–652.
    3. DOI: 10.1002/adsc.201200949
  71. Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes.
    1. Shido, Y.; Yoshida M.; Tanabe, M.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2012, 134, 18573–18576.
    3. DOI: 10.1021/ja3093955
  72. Conjugate Reduction of α,β-Unsaturated Carbonyl and Carboxyl Compounds with Poly(methylhydrosiloxane) Catalyzed by a Silica-Supported Compact Phosphane-Copper Complex.
    1. Kawamorita, S.; Yamazaki, K.; Ohmiya, H.; Iwai, T.; Sawamura, M. Adv. Synth. Catal. 2012, 354, 3440–3444.
    2. DOI: 10.1002/adsc.201200555
  73. Rh-Catalyzed Borylation of N-Adjacent C(sp3)-H Bonds with a Silica-Supported Triarylphosphine Ligand.
    1. Kawamorita, S.; Miyazaki, T.; Iwai, T.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2012, 134, 12924–12927.
    3. DOI: 10.1021/ja305694r
  74. Synthesis of Allenylsilanes through Copper-Catalyzed γ-Selective Coupling between γ-Silylated Propargylic Phosphates and Alkylboranes.
    1. Yokobori, U.; Ohmiya, H.; Sawamura, M.
    2. Organometallics 2012, 31, 7909–7913.
    3. DOI: 10.1021/om300552f
  75. Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper-N-Heterocyclic Carbene Complex.
    1. Yoshida, M.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2012, 134, 11896–11899.
    3. DOI: 10.1021/ja304481a
  76. Reversible 1,3-Anti/Syn Stereochemical Courses in Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes.
    1. Nagao, K.; Yokobori, U.; Makida, Y.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2012, 134, 8982–8987.
    3. DOI: 10.1021/ja302520h
  77. Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes.
    1. Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Synthesis 2012, 44, 1535–1541.
    3. DOI: 10.1055/s-0031-1290818
  78. Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation.
    1. Makida, Y.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2012, 51, 4122–4127.
    3. DOI: 10.1002/anie.201200809
  79. Synthesis of Conjugated Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates.
    1. Yang, M.; Yokokawa, N.;Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2012, 14, 816–819.
    3. DOI: 10.1021/ol2033465
  80. Efficient Preparation of β-Branched γ,δ -Unsaturated Esters through Copper-Catalyzed Allylic Alkylation of Ketene Silyl Acetal.
    1. Li, D.; Ohmiya, H.; Sawamura, M. Synthesis 2012, 44, 1304–1307.
    2. DOI: 10.1055/s-0031-1289712
  81. Rh-Catalyzed Ortho-Selective C-H Borylation of N-Functionalized Arenes with Silica-Supported Bridgehead Monophosphine Ligands.
    1. Kawamorita, S.; Miyazaki, T.; Ohmiya, H.; Iwai, T.; Sawamura, M.
    2. J. Am. Chem. Soc. 2011, 133, 19310–19313.
    3. DOI: 10.1021/ja208364a
  82. General Approach to Allenes through Copper-Catalyzed gannma γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Alkylboranes.
    1. Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M.
    2. Org. Lett. 2011, 13, 6312–6315.
    3. DOI: 10.1021/ol202866h
  83. Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with Silica-Supported Compact Phosphane Ligand.
    1. Kawamorita, S.; Ohmiya, H.; Iwai, T.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2011, 50, 8363–8366 (VIP).
    3. DOI: 10.1002/anie.201103224
  84. Intramolecular Hydroamination of Alkynic Sulfonamides Catalyzed by Gold-Triethynylphosphine Complex: Construction of Azepine Frameworks by 7-Exo-dig Cyclization.
    1. Ito, H.; Harada, T.; Ohmiya, H.; Sawamura, M.
    2. Beilstein. J. Org. Chem. 2011, 7, 951–959.
    3. DOI: 10.3762/bjoc.7.106
  85. Copper-Catalyzed Conjugate Additions of Alkylboranes to Aryl α,β-Unsaturated Ketones.
    1. Ohmiya, H.; Shido, Y.; Yoshida, M.; Sawamura, M.
    2. Chem. Lett. 2011, 40, 928–930.
    3. DOI: 10.1246/cl.2011.928
  86. Copper-Catalyzed γ-Selective and Stereospecific Allylic Alkylation of Ketene Silyl Acetals.
    1. Li, D.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2011, 133, 5672–5675.
    3. DOI: 10.1021/ja111645q
  87. Copper-Catalyzed Carboxylation of Alkylboranes with Carbon Dioxide: Formal Reductive Carboxylation of Terminal Alkenes.
    1. Ohmiya, H.; Tanabe, M.; Sawamura, M.
    2. Org. Lett. 2011, 13, 1086–1088.
    3. DOI: 10.1021/ol103128x
  88. Copper-Catalyzed Conjugate Additions of Alkylboranes to Imidazolyl α,β-Unsaturated Ketones: Formal Reductive Conjugate Addition of Terminal Alkenes.
    1. Ohmiya, H.; Yoshida, M.; Sawamura, M.
    2. Org. Lett. 2011, 13, 482–485.
    3. DOI: 10.1021/ol102819k
  89. Sulfonamidoquinoline-Palladium(II) Dimer Complex As a Catalyst Precursor for Palladium-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling Reaction between Allylic Acetates and Arylboronic Acids.
    1. Makida, Y.; Ohmiya, H.; Sawamura, M.
    2. Chem. Asian J. 2011, 6, 410–414.
    3. DOI: 10.1002/asia.201000721
  90. Construction of Methylenecycloheptane Frameworks through 7-Exo-dig Cyclization of Acetylenic Silyl Enol Ethers Catalyzed by Triethynylphosphine-Gold Complex.
    1. Ito, H.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2010, 12, 4380–4383.
    3. DOI: 10.1021/ol101860j
  91. Directed Ortho Borylation of Phenol Derivatives Catalyzed by a Silica-Supported Iridium Complex.
    1. Yamazaki, K.; Kawamorita, S.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2010, 12, 3978–3981.
    3. DOI: 10.1021/ol101493m
  92. Protecting-Group-Free Route to Hydroxylated Pyrrolidine and Piperidine Derivatives through Cu(I)-Catalyzed Intramolecular Hydroamination of Alkenes.
    1. Ohmiya, H.; Yoshida, M.; Sawamura, M.
    2. Synlett 2010, 2136–2140.
    3. DOI: 10.1055/s-0030-1258527
  93. Synthesis of α-Arylated Allylsilanes through Palladium-Catalyzed γ-Selective Allyl-Aryl Coupling.
    1. Li, D.; Tanaka, T.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2010, 12, 3344–3347.
    3. DOI: 10.1021/ol101114r
  94. Copper-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling between (Z)-Acyclic and Cyclic Allylic Phosphates and Arylboronates.
    1. Ohmiya, H.; Yokokawa, N.; Sawamura, M.
    2. Org. Lett. 2010, 12, 2438–2440.
    3. DOI: 10.1021/ol100841y
  95. Ester-Directed Regioselective Borylation of Heteroarenes Catalyzed by a Silica-Supported Iridium Complex.
    1. Kawamorita, S.; Ohmiya, H.; Sawamura, M.
    2. J. Org. Chem. 2010, 75, 3855–3858.
    3. DOI: 10.1021/jo100352b
  96. Selective Synthesis of Allenes and Alkynes through Ligand-Controlled, Palladium-Catalyzed Decarboxylative Hydrogenolysis of Propargylic Formates.
    1. Ohmiya, H.; Yang, M.; Yamauchi, Y.; Ohtsuka, Y.; Sawamura, M.
    2. Org. Lett. 2010, 12, 1796–1799.
    3. DOI: 10.1021/ol100405k
  97. Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes.
    1. Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M.
    2. J. Am. Chem. Soc. 2010, 132, 2895–2897.
    3. DOI: 10.1021/ja9109105
  98. Palladium-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling between Acyclic Allylic Esters and Arylboronic Acids.
    1. Ohmiya, H.; Makida, Y.; Li, D.; Tanabe, M.; Sawamura, M.
    2. J. Am. Chem. Soc. 2010, 132, 879–889.
    3. DOI: 10.1021/ja9092264
  99. General and Functional Group-Tolerable Approach to Allenylsilanes by Rhodium-Catalyzed Coupling between Propargylic Carbonates and a Silylboronate.
    1. Ohmiya, H.; Ito, H.; Sawamura, M.
    2. Org. Lett. 2009, 11, 5618–5620.
    3. DOI: 10.1021/ol902339a
  100. Cu(I)-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes Bearing a Primary or Secondary Amino Group in Alcoholic Solvents.
    1. Ohmiya, H.; Moriya, T.; Sawamura, M.
    2. Org. Lett. 2009, 11, 2145–2147.
    3. DOI: 10.1021/ol9007712
  101. Directed ortho-Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine-Iridium System.
    1. Kawamorita, S.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M.
    2. J. Am. Chem. Soc. 2009, 131, 5058–5059.
    3. DOI: 10.1021/ja9008419
  102. Palladium-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling between Allylic Acetates and Arylboronic Acids.
    1. Ohmiya, H.; Makida, Y.; Tanaka, T.; Sawamura, M.
    2. J. Am. Chem. Soc. 2008, 130, 17276–17277.
    3. DOI: 10.1021/ja808673n
  103. Cyclization of Non-Terminal Alkynic β-Keto Esters Catalyzed by Gold(I) Complex with a Semihollow, End-Capped Triethynylphosphine Ligand.
    1. Ito, H.; Makida, Y.; Ochida, A.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2008, 10, 5051–5054.
    3. DOI: 10.1021/ol802079r
  104. Synthesis of Silica-Supported Compact Phosphines and Their Application to Rhodium-Catalyzed Hydrosilylation of Hindered Ketones with Triorganosilanes.
    1. Hamasaka, G.; Kawamorita, S.; Ochida, A.; Akiyama, R.; Hara, K.; Fukuoka, A.; Asakura, K.; Chun, W. J.; Ohmiya, H.; Sawamura, M.
    2. Organometallics 2008, 27, 6495–6506.
    3. DOI: 10.1021/om800683g
  105. Hydrogenation of Hindered Ketones Catalyzed by a Silica-Supported Compact Phosphine-Rh System.
    1. Kawamorita, S.; Hamasaka, G.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M.
    2. Org. Lett. 2008, 10, 4697–4700.
    3. DOI: 10.1021/ol801996r
  106. Synthesis, Properties and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane.
    1. Ochida, A.; Hamasaka, G.; Yamauchi, Y.; Kawamorita, S.; Oshima, N.; Hara, K.; Ohmiya, H.; Sawamura, M.
    2. Organometallics 2008, 27, 5494–5503.
    3. DOI: 10.1021/om8005728
  107. Cobalt-Catalyzed Regioselective Dehydrohalogenation of Alkyl Halides with Dimethylphenylsilylmethylmagnesium Chloride.
    1. Kobayashi, T.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. J. Am. Chem. Soc. 2008, 130, 11276–11277.
    3. DOI: 10.1021/ja804277x
  108. Silver-Catalyzed Benzylation and Allylation Reactions of Alkyl Halides with Grignard Reagents.
    1. Someya, H.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Org. Lett. 2008, 10, 969–971.
    3. DOI: 10.1021/ol800038a
  109. Generation of Rhodium Enolates via Retro-Aldol Reaction and Its Application to Regioselective Aldol Reaction.
    1. Murakami, K.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Tetrahedron Lett. 2008, 49, 2388–2390.
    3. DOI: 10.1016/j.tetlet.2008.02.062
  110. Alpha Olefins as Alkenylmetal Equivalents in Catalytic Conjugate Addition Reactions.
    1. Ho, C.-Y.; Ohmiya, H.; Jamison, T. F.
    2. Angew. Chem. Int. Ed. 2008, 47, 1893–1895.
    3. DOI: 10.1002/anie.200705163
  111. N-Heterocyclic Carbene Ligands in Cobalt-Catalyzed Sequential Cyclization/Cross-Coupling Reactions of 6-Halo-1-hexene Derivatives with Grignard Reagents.
    1. Someya, H.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Org. Lett. 2007, 9, 1565–1567.
    3. DOI: 10.1021/ol070392f
  112. Cobalt-Catalyzed Sequential Cyclization/Cross-Coupling Reactions of 6-Halo-1-hexene Derivatives with Grignard Reagents and Their Application to the Synthesis of 1,3-Diols.
    1. Someya, H.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Tetrahedron 2007, 63, 8609–8618.
    3. DOI: 10.1016/j.tet.2007.04.083
  113. Chromium-Catalyzed Arylmagnesiation of Alkynes.
    1. Murakami, K.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Org. Lett. 2007, 9, 1569–1571.
    3. DOI: 10.1021/ol0703938
  114. Nickel-Catalyzed Carbometalation Reactions of [2-(1-Propynyl)phenyl]methanol with 1-Alkenylmagnesium Reagents.
    1. Murakami, K.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Chem. Lett. 2007, 36, 1066–1067.
    3. DOI: 10.1246/cl.2007.1066
  115. A New Approach to 4-Aryl-1,3-butanediols by Cobalt-Catalyzed Sequential Radical Cyclization/Arylation Reaction of Silicon-tethered 6-Iodo-1-hexene Derivatives.
    1. Someya, H.; Kondoh, A.; Sato, A.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Synlett 2006, 18, 3061–3064.
    3. DOI: 10.1055/s-2006-951508
  116. Cobalt(diamine)-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Arylmagnesium Reagents: Stereoselective Constructions of Arylated Asymmetric Carbons and Application to Total Synthesis of AH13205.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. J. Am. Chem. Soc. 2006, 128, 1886–1889.
    3. DOI: 10.1021/ja057560o
  117. Cobalt-Mediated Cross-Coupling Reactions of Primary and Secondary Alkyl Halides with 1-Trimethylsilylethenyl- and 2-Trimethylsilylethynylmagnesium Reagents.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Org. Lett. 2006, 8, 3093–3096.
    3. DOI: 10.1021/ol0611144
  118. Cobalt-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Aryl Grignard Reagents and Their Application to Sequential Radical Cyclization/Cross-Coupling Reactions.
    1. Ohmiya, H.; Wakabayashi, K.; Yorimitsu, H.; Oshima, K.
    2. Tetrahedron 2006, 62, 2207–2213.
    3. DOI: 10.1016/j.tet.2005.12.013
  119. Cobalt-Catalyzed Trimethylsilylmethylmagnesium-Promoted Radical Alkenylation of Alkyl Halides: A Complement to the Heck Reaction.
    1. Affo, W.; Ohmiya, H.; Fujioka, T.; Ikeda, Y.; Nakamura, T.; Yorimitsu, H.; Oshima, K.; Imamura, Y.; Mizuta, T.; Miyoshi, K.
    2. J. Am. Chem. Soc. 2006, 128, 8068–8077.
    3. DOI: 10.1021/ja061417t
  120. Cobalt-Catalyzed Syn-Hydrophosphination of Alkynes.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Angew. Chem. Int. Ed. 2005, 44, 2368–2370.
    3. DOI: 10.1002/anie.200500255
  121. Regio- and Stereoselective Approach to 1,2-Di- and 1,1,2-Trisilylethenes by Cobalt-Mediated Reaction of Silyl-Substituted Dibromomethanes with Silylmethylmagnesiums.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Angew. Chem. Int. Ed. 2005, 44, 3488–3490.
    3. DOI: 10.1002/anie.200500576
  122. Cobalt-Catalyzed Cross-Coupling Reaction of Chloropyridines with Grignard Reagents.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Chem. Lett. 2004, 33, 1240–1241.
    3. DOI: 10.1246/cl.2004.1240
  123. Cobalt-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Allylic and Benzylic Grignard Reagents and Their Application to Tandem Radical Cyclization/Cross-Coupling Reaction.
    1. Ohmiya, H.; Tsuji, T.; Yorimitsu, H.; Oshima, K. Chem. Eur. J. 2004, 10, 5640–5648.
    2. DOI: 10.1002/chem.200400545
  124. Novel Synthesis of 5-Thio-hexopyranoside: Preparation of 5-Thio-D- and L-glucose and 1,6-Anhydro-5-thio-L- and D-altrose.
    1. Uenishi, J. i.; Ohmiya, H.
    2. Tetrahedron 2003, 59, 7011–7022.
    3. DOI: 10.1016/S0040-4020(03)00864-0
  125. Studies on Stereoselective Sonogashira Coupling of 1,1-Dibromo-1-alkene.
    1. Uenishi, J. i.; Matsui, K.; Ohmiya, H.
    2. J. Organomet. Chem. 2002 , 653, 141–149.
          1. DOI: 10.1016/S0022-328X(02)01262-7

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