Publication

Prof. Dr. Hirohisa Ohmiya

Original publications

  1. Radical C-Glycosylation Using Photoexcitable Unprotected Glycosyl Borate
    1. Miyamoto, Y.; Murakami, S.; Sumida, Y.; Hirai, G.; Ohmiya, H.
    2. Chem. Eur. J. 2024, 30, e202402256.
    3. DOI: 10.1002/chem.202402256
  2. Deoxygenative Geminal Silylboration of Amides Using Silylboronates: Synthesis and Use of α-Boryl-α-Silylalkylamines
    1. Watanabe, K.; Nagao, K.; Ohmiya, H.
    2. Angew. Chem. Int. Ed. 2024, 63, e202411990.
    3. DOI: 10.1002/anie.202411990
    4. ChemRxiv. 2024
    5. DOI: 10.26434/chemrxiv-2024-55nn
  3. γ-Amino C(sp3)–H Functionalization of Aliphatic Amines through a Light-Driven Triple Catalysis
    1. Nakagawa, M.; Nagao, K.; Ohmiya, H.
    2. ACS Catal. 2024, 14, 8005–8012.
    3. DOI: 10.1021/acscatal.4c0200
    4. Most Read Articles (1 month)
  4. Use of Aliphatic Carboxylic Acid Derivatives for NHC/Photoredox-Catalyzed meta-Selective Acylation of Electron-Rich Arenes
    1. Goto, Y.; Murakami, S.; Sumida, Y.; Ohmiya, H.
    2. Synthesis 2024, 56, 3327–3333 (Special Issue 10th Pacific Symposium on Radical Chemistry (PSRC-10)).
    3. DOI: 10.1055/a-2281-2975
  5. A Dual Cobalt and Photoredox Catalysis for Hydrohalogenation of Alkenes
    1. Shibutani, S.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2024, 146, 4375–4379.
    3. DOI: 10.1021/jacs.3c10133
    4. Most Read Articles (1 month)
    6. Kyoto univ. press release
  6. Synthesis of Tertiary Alkylphosphonate Oligonucleotides through Light-Driven Radical-Polar Crossover Reactions
    1. Ota, K.; Nagao, K.; Hata, D.; Sugiyama, H.; Segawa, Y.; Tokunoh, R.;  Seki, T.; Miyamoto, N.; Sasaki, Y.; Ohmiya, H.
    2. Nat. Commun. 2023, 14, 6856.
    3. DOI: 10.1038/s41467-023-42639-y
    5. Kyoto univ. and IMS press release
  7. Biomimetic Design of an a-Ketoacylphosphonium-Based Light-Activated Oxygenation Auxiliary
    1. Oya, R.; Ota, K.; Fuki, M.; Kobori, Y.; Higashi, M.; Nagao, K.; Ohmiya, H.
    2. Chem. Sci. 2023, 14, 10488–10493.
    3. DOI: 10.1039/D3SC03572G
  8. Diastereoselective Congested β-Amido Ketone Synthesis via NHC-Catalyzed Radical–Radical Coupling
    1. Sato, Y.; Miyamoto, Y.; Matsui, T.; Sumida, Y.; Ohmiya, H.
    2. Chem Catal. 2023, 3, 100736.
    3. DOI: 10.1016/j.checat.2023.100736
    4. ChemRxiv. 2023
    5. DOI: 10.26434/chemrxiv-2023-wbm3p
  9. N-Heterocyclic Carbene- and Organic Photoredox-Catalysed meta-Selective Acylation of Electron-Rich Arenes
    1. Goto, Y.; Sano, M.; Sumida, Y.; Ohmiya, H.
    2. Nat. Synth. 2023, 2, 1037–1045.
    3. DOI: 10.1038/s44160-023-00378-4
    4. ChemRxiv. 2023
    5. DOI: 10.26434/chemrxiv-2023-1p1kv-v2
    7. Kyoto univ. and JST press release    Highlighted in Synform
  10. A Quadruple Catalysis Enabling Intermolecular Branch-Selective Hydroacylation of Styrenes
    1. Takekawa, Y.; Nakagawa, M.; Nagao, K.; Ohmiya, H.
    2. Chem. Eur. J. 2023, 29, e202301484 (Very Important Papers).
    3. DOI: 10.1002/chem.202301484
  11. Radical Caging Strategy for Cholinergic Optopharmacology
    1. Nakamura, R.; Yamazaki,T.; Kondo, Y.; Tsukada, M.; Miyamoto,Y.; Arakawa,N.; Sumida, Y.; Kiya, T.; Arai, S.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2023, 145, 10651–10658.
    3. DOI: 10.1021/jacs.3c00801
    5. Kyoto univ. and Kanazawa univ. press release
  12. Light-Driven Radical-Polar Crossover Catalysis Enabling Decarboxylative Fluorination of Redox Active Esters
    1. Takekawa, Y.; Kodo, T.; Nagao, K.; Kakei, H.; Takeuchi, K.; Sasaki, Y.; Ohmiya, H.
    2. Chem. Lett. 2023, 52, 41–43.
    3. DOI: 10.1246/cl.220472
  13. Light-Driven Radical-Polar Crossover Catalysis for Cross-Coupling with Organosilanes
    1. Matsuo, T.; Nagao, K.; Ohmiya, H.
    2. Tetrahedron Lett. 2022, 112, 154231 (Special Issue on “Recent Advances in Photocatalysis for Selective Organic Synthesis”).
    3. DOI: 10.1016/j.tetlet.2022.154231
  14. Organic Photoredox-Catalyzed Silyl Radical Generation from Silylboronate
    1. Takemura, N.; Sumida, Y.; Ohmiya, H.
    2. ACS Catal. 2022, 12, 7804–7810.
    3. DOI: 10.1021/acscatal.2c01964
    4. Most Read Articles (1 month)
  15. Direct Photoexcitable Iodomethylborate Enabling Cyclopropanation of Reactive Alkenes
    1. Nakamura, R.; Sumida, Y.; Ohmiya, H.
    2. Bull. Chem. Soc. Jpn. 2022 , 95, 1001–1005 (Selected Paper).
    3. DOI: 10.1246/bcsj.20220112
  16. Organophotoredox-Catalyzed Semipinacol Rearrangement via Radical-Polar Crossover
    1. Kodo, T.; Nagao, K.; Ohmiya, H.
    2. Nat. Commun. 2022, 13, 2684.
    3. DOI: 10.1038/s41467-022-30395-4
    5. Kyoto univ., Kanazawa univ. and JST press release
  17. A Triple Photoredox/Cobalt/Bronsted Acid Catalysis Enabling Markovnikov Hydroalkoxylation of Unactivated Alkenes
    1. Nakagawa, M.; Matsuki, Y.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2022, 144, 7953–7959.
    3. DOI: 10.1021/jacs.2c00527
    4. Most Read Articles (1 month)
    6. Kyoto univ. and Kanazawa univ. press release   EurekAlert!
  18. Reductive Cross-Coupling between Arylaldehydes and (Hetero)aryl Electrophiles Using Silylboronate Reductant
    1. Watanabe, K.; Takeda, M.; Nagao, K.; Ohmiya, H.
    2. Eur. J. Org. Chem. 2022, e202200005 (Virtual Special Collection on “Silicon Chemistry in Organic Synthesis”).
    3. DOI: 10.1002/ejoc.202200005
  19. Molecular Field Analysis Using Computational-Screening Data in Asymmetric N-Heterocyclic Carbene-Copper Catalysis toward Data-driven in silico Catalyst Optimization
    1. Mukai, M.; Nagao, K.; Yamaguchi, S.; Ohmiya, H.
    2. Bull. Chem. Soc. Jpn. 2022 , 95, 271–277 (Selected Paper).
    3. DOI: 10.1246/bcsj.20210349
    5. Riken and Kanazawa univ. press release
  20. Direct Photoexcitation of Borate Enabling Minisci Reaction
    1. Kemmochi, M.; Miyamoto, Y.; Sumida, Y.; Ohmiya, H.
    2. Asian. J. Org. Chem. 2022, 11, e202100640 (AsianJOCs 10th Anniversary Special Collection).
    3. DOI: 10.1002/ajoc.202100640
  21. Light-Driven N-Heterocyclic Carbene Catalysis Using Alkylborates
    1. Sato, Y.; Goto, Y.; Nakamura, K.; Miyamoto, Y.; Sumida, Y.; Ohmiya, H.
    2. ACS Catal. 2021, 11, 12886–12892.
    3. DOI: 10.1021/acscatal.1c04153
    4. Most Read Articles (1 month)
  22. Radical Relay Trichloromethylacylation of Alkenes through N-Heterocyclic Carbene Catalysis
    1. Kusakabe, M.; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 7242–7247.
    3. DOI: 10.1021/acs.orglett.1c02639
  23. Organophotoredox-Catalyzed Decarboxylative N-Alkylation of Sulfonamides
    1. Nakagawa, M.; Nagao, K.; Ikeda, Z.; Reynolds, M.; Ibáñez, I.; Wang, J.; Tokunaga, N.; Sasaki, Y.; Ohmiya, H.
    2. ChemCatChem 2021, 13, 3930–3933 (part of a joint Special Collection with EurJIC on “Main Group Catalysis”)
    3. DOI: 10.1002/cctc.202100803
  24. Generation of Functionalized Alkyl Radicals via the Direct Photo-Excitation of PDP-Based Borates
    1. Miyamoto, Y.; Sumida, Y.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 5865–5870.
    3. DOI: 10.1021/acs.orglett.1c01996
    4. Most Read Articles (1 month)
  25. Aryl Radical-Mediated N-Heterocyclic Carbene Catalysis
    1. Matsuki, Y.; Ohnishi, N.; Kakeno, Y.; Takemoto, S.; Ishii, T.; Nagao, K.; Ohmiya, H.
    2. Nat. Commun. 2021, 12, 3848.
    3. DOI: 10.1038/s41467-021-24144-2
    5. Kanazawa univ. and JST press release   EurekAlert!　Asian Research News　Science Japan
  26. Decarboxylative N-Alkylation of Azoles Through Visible-Light-Mediated Organophotoredox Catalysis
    1. Kobayashi, R.; Shibutani, S.; Nagao, K.; Ikeda, Z.; Wang, J.; Ibáñez, I.; Reynolds, M.; Sasaki, Y.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 5415–5419 (Supplementary Cover ).
    3. DOI: 10.1021/acs.orglett.1c01745
    4. Most Read Articles (1 month)
  27. Synthesis of Sterically Hindered α-Hydroxycarbonyls through Radical–Radical Coupling
    1. Ota, K.; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 4420–4425.
    3. DOI: 10.1021/acs.orglett.1c01358
    4. Most Read Articles (1 month)
  28. Radical N-Heterocyclic Carbene Catalysis for β-Ketocarbonyl Synthesis
    1. Ishii, T.; Nagao, K.; Ohmiya, H.
    2. Tetrahedron 2021, 91, 132212 (Special Issue on System-Oriented Development of Organocatalysis).
    3. DOI: 10.1016/j.tet.2021.132212
  29. Fluorescent-oxaboroles: Synthesis and Optical Property by Sugar Recognition
    1. Nakano, M.; Nakamura, R.; Sumida, Y.; Nagao, K.; Furuyama, T.; Inagaki, F.; Ohmiya, H.
    2. Chem. Pharm. Bull. 2021, 69, 526–528 (Featured Article).
    3. DOI: 10.1248/cpb.c21-00179
    4. Most viewed articles Jun.2021
  30. Catalytic Reductive Cross-Coupling between Aromatic Aldehydes and Arylnitriles
    1. Mitsui, A.; Nagao, K.; Ohmiya, H.
    2. Chem. Eur. J. 2021, 27, 7094–7098.
    3. DOI: 10.1002/chem.202100763
  31. Organophotoredox-Catalyzed Three-Component Coupling of Heteroatom Nucleophiles, Alkenes, and Aliphatic Redox Active Esters
    1. Shibutani, S.; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2021, 23, 1798-1803.
    3. DOI: 10.1021/acs.orglett.1c00211
    4. Most Read Articles (1 month)
  32. Transition-Metal-Free Cross-Coupling Using Tertiary Benzylic Organoboronates
    1. Takeda, M.; Nagao, K.; Ohmiya, H.
    2. Angew. Chem. Int. Ed. 2020, 59, 22460–22464.
    3. DOI: 10.1002/anie.202010251
    5. EurekAlert!
  33. Boracene-Based Alkylborate Enabling Ni/Ir Hybrid Catalysis
    1. Sato, Y.; Miyamoto, Y.; Sumida, Y.; Hosoya, T.; Ohmiya, H.
    2. Org. Biomol. Chem. 2020, 18, 6598–6601 (Themed Issue on Hybrid Catalysis).
    3. DOI: 10.1039/D0OB01610A
  34. Direct Synthesis of Dialkyl Ketones from Aliphatic Aldehydes through Radical N-Heterocyclic Carbene Catalysis
    1. Kakeno, Y.; Kusakabe, M.; Nagao, K.; Ohmiya, H.
    2. ACS Catal. 2020, 10, 8524–8529.
    3. DOI: 10.1021/acscatal.0c02849
    4. Most Read Articles (1 month)
    6. Kanazawa univ. and JST press release   EurekAlert!　Asian Research News
  35. Reductive Umpolung for Asymmetric Synthesis of Chiral α-Allenic Alcohols
    1. Kondo, Y.; Nagao, K.; Ohmiya, H.
    2. Chem. Commun. 2020, 56, 7471–7474.
    3. DOI: 10.1039/D0CC02619K
  36. Generation of Alkyl Radical through Direct Excitation of Boracene-Based Alkylborate
    1. Sato, Y.; Nakamura, K.; Sumida, Y.; Hashizume, D.; Hosoya, T.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2020, 142, 9938–9943.
    3. DOI: 10.1021/jacs.0c04456
    4. Most Read Articles (1 month)
    6. Kanazawa univ. press release　EurekAlert!　Asian Research News　Chem-Station　Nature Index
  37. Tertiary Alkylations of Aldehydes, Ketones or Imines Using Benzylic Organoboronates and a Base Catalyst
    1. Sato, Y.; Nakamura, K.; Yabushita, K.; Nagao, K.; Ohmiya, H.
    2. Bull. Chem. Soc. Jpn. 2020, 93, 1065–1069.
    3. DOI: 10.1246/bcsj.20200122
  38. N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Synthesis of δ-Ketocarbonyls
    1. Ota, K; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2020, 22, 3922–3925.
    3. DOI: 10.1021/acs.orglett.0c01199
    4. Most Read Articles (1 month)
    6. Highlighted in Synfacts
  39. Aliphatic Oxaboroles Enabling Remarkable Recognition of Diol
    1. Arakawa, N.; Nagao, K.; Murakami, R.; Sumida, Y.; Arakawa, H.; Inagaki, F.; Ohmiya, H.
    2. Bull. Chem. Soc. Jpn. 2020​, 93, 576–580 (Selected Paper).
    3. DOI: 10.1246/bcsj.20200007
  40. Allylic Cross-Coupling Using Aromatic Aldehydes as α-Alkoxyalkyl Anions
    1. Yuasa, A; Nagao, K.; Ohmiya, H.
    2. Beilstein J. Org. Chem. 2020, 16, 185–189 (Thematic issue “Copper-catalyzed reactions for organic synthesis”).
    3. DOI: 10.3762/bjoc.16.21
  41. Copper-Catalyzed Enantioselective Reductive Cross-Coupling of Aldehydes and Imines
    1. Mitsui, A.; Nagao, K.; Ohmiya, H.
    2. Org. Lett. 2020, 22, 800–803.
    3. DOI: 10.1021/acs.orglett.9b04144
  42. Organophotoredox-Catalyzed Decarboxylative C(sp3)–O Bond Formation
    1. Shibutani, S.; Kodo, T.; Takeda, M.; Nagao, K.; Tokunaga, N.; Sasaki, Y.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2020, 142, 1211–1216.
    3. DOI: 10.1021/jacs.9b12335
    4. Most Read Articles (1 month and 12 month)
    6. Highlighted in Synfacts
  43. N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes
    1. Ishii, T.; Ota, K.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2019, 141, 14073–14077.
    3. DOI: 10.1021/jacs.9b07194
    4. Most Read Articles (1 month)
    6. Kanazawa univ. press release　EurekAlert!　Highlighted in Synfacts
  44. Synergistic N-Heterocyclic Carbene/Palladium Catalyzed Aldehyde Acylation of Allylic Amines
    1. Ohnishi, N.; Yasuda, S.; Nagao, K.; Ohmiya, H.
    2. Asian. J. Org. Chem. 2019, 8, 1133–1135 (Special Issue: Heterocyclic Chemistry).
    3. DOI: 10.1002/ajoc.201900303
    4. Top Downloaded Paper 2018–2019
  45. Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand
    1. Imai, K.; Takayama, H.; Murayama, H.; Ohmiya, H.; Shimizu Y.; Sawamura, M.
    2. Org. Lett. 2019, 21, 1717–1721.
    3. DOI: 10.1021/acs.orglett.9b00276
  46. N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes
    1. Ishii, T.; Kakeno, Y.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2019, 141, 3854–3858.
    3. DOI: 10.1021/jacs.9b00880
    4. Most Read Articles (1 month and 12 month)
    6. Kanazawa univ. press release　Highlighted in ChemistryViews　EurekAlert!　Highlighted in Synfacts
    7. Highlighted in Angew. Chem. Int. Ed.
  47. Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Allylation of Aldehydes with Allylic Carbonates
    1. Takemoto, S.; Ishii, T.; Yasuda, S.; Ohmiya, H.
    2. Bull. Chem Soc. Jpn. 2019, 92, 937–940 (Selected Paper).
    3. DOI: 10.1246/bcsj.20190012
  48. Reductive Coupling between Aromatic Aldehydes and Ketones or Imines by Copper Catalysis
    1. Takeda, M.; Mitsui, A.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2019, 141, 3664–3669 (Supplementary Cover ).
    3. DOI: 10.1021/jacs.8b13309
    4. Most Read Articles (1 month)
    6. Kanazawa univ. press release　EurekAlert!　Chem-Station
  49. Asymmetric Catalysis Using Aromatic Aldehydes as Chiral α-Alkoxyalkyl Anions
    1. Yabushita, K.; Yuasa, A.; Nagao, K.; Ohmiya, H.
    2. J. Am. Chem. Soc. 2019, 141, 113–117.
    3. DOI: 10.1021/jacs.8b11495
    4. Most Read Articles (1 month)
    6. Kanazawa univ. press release　EurekAlert!
  50. Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis
    1. Haruki, H.; Yasuda, S.; Nagao, K.; Ohmiya, H.
    2. Chem. Eur. J. 2019, 25, 724–727 (Front Cover , Cover Profile ).
    3. DOI: 10.1002/chem.201805955
    4. Top Downloaded Paper 2018–2019
    6. EurekAlert!
  51. Synergistic Palladium/Copper-Catalyzed Csp3–Csp2 Cross-Couplings Using Aldehydes As Latent α-Alkoxyalkyl Anion Equivalents.
    1. Takeda, M.; Yabushita, K.; Yasuda, S.; Ohmiya, H.
    2. Chem. Commun. 2018, 54, 6776–6779 (Back Cover, Emerging Investigators 2018 Issue).
    3. DOI: 10.1039/c8cc01055b
  52. Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Reactions of Aldehyde Acyl Anions with either Diarylmethyl or Allylic Carbonates.
    1. Yasuda, S.; Ishii, T.; Takemoto, S.; Haruki, H.; Ohmiya, H.
    2. Angew. Chem. Int. Ed. 2018, 57, 2938–2942.
    3. DOI: 10.1002/anie.201712811
    5. Kanazawa univ. press release　EurekAlert! 　Chem-Station
  53. Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes
    1. Nagao, N.; Yamazaki, A.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2018, 20, 1861–1865.
    3. DOI: 10.1021/acs.orglett.8b00390
  54. Enantiocontrol by Assembled Attractive Interactions in Copper-catalyzed Asymmetric Direct Alkynylation of  α-Ketoesters with Terminal Alkynes: OH···O/sp3-CH···O Two-point Hydrogen-bonding Combined with Dispersive Attractions
    1. Schwarzer, M. C.; Fujioka, A.; Ishii, T.; Ohmiya, H.; Mori, S.; Sawamura, M.
    2. Chem. Sci. 2018, 9, 3484–3493.
    3. DOI: 10.1039/C8SC00527C
  55. Copper-Catalyzed Enantioselective Intramolecular Alkylboron Allylic Alkylation
    1. Hojoh, K.; Shido, Y.; Ohmiya, H.; Sawamura, M.
    2. Chem. Lett. 2018, 47, 632–635..
    3. DOI: 10.1246/cl.180147
  56. Copper-Catalyzed Enantioselective Coupling between Allylboronates and Phosphates with a Phenol-Carbene Chiral Ligand: Asymmetric Synthesis of Chiral Branched 1,5-Dienes
    1. Yasuda, Y.; Ohmiya, H.; Sawamura, M.
    2. Synthesis 2018, 50, 2235–2246.
    3. DOI: 10.1055/s-0036-1591548
  57. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multi-Substituted γ-Borylallylboranes
    1. Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2018, 57, 3196–3199.
    3. DOI: 10.1002/anie.201712351
  58. Asymmetric Synthesis of β-Lactams through Copper-Catalyzed Alkyne–Nitrone Coupling with Prolinol-Phosphine Chiral Ligand.
    1. Takayama, Y.; Ishii, T.; Ohmiya, H.; Iwai, T.; Schwarzer, M. C.; Mori, S.; Taniguchi, T.; Monde, K.; Sawamura, M.
    2. Chem. Eur. J. 2017, 23, 8400–8404.
    3. DOI: 10.1002/chem.201702070
  59. Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides
    1. Hojoh, K.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2017, 139, 2184-2187.
    3. DOI: 10.1021/jacs.6b12881
  60. Copper-Catalyzed Enantioselective Allyl-Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand
    1. Yasuda, Y.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2016 , 55, 10816–10820.
    2. DOI: 10.1002/anie.201605125
  61. Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates
    1. Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2016, 18, 1706–1709.
    3. DOI: 10.1021/acs.orglett.6b00677
  62. Copper-Catalyzed Semihydrogenation of Internal Alkynes with Molecular Hydrogen
    1. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Organometallics 2016, 35, 1354–1357.
    3. DOI: 10.1021/acs.organomet.6b00126
  63. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles
    1. Ohmiya, H.; Zhang, H.; Shibata, S.; Harada, A.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2016, 55, 4777–4780.
    3. DOI: 10.1002/anie.201600619
  64. Copper-Catalyzed Stereoselective Conjugate Addition of Alkylboranes to Alkynoates.
    1. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Beilstein J. Org. Chem. 2015, 11, 2444–2450.
    3. DOI: 10.3762/bjoc.11.265
  65. Silica-supported Triptycene-type Phosphine. Synthesis, Characterization, and Application to Pd-Catalyzed Suzuki-Miyaura Cross-coupling of Chloroarenes.
    1. Iwai, T.; Konishi, S.; Miyazaki, T.; Kawamorita, S.; Yokokawa, N.; Ohmiya, H.; Sawamura, M.
    2. ACS Catal. 2015, 5, 7254–7264.
    3. DOI: 10.1021/acscatal.5b00904
  66. Synthesis of 1,1-Diborylalkenes through a Bronsted-base-catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron.
    1. Morinaga, A.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2015, 54, 15859–15862.
    3. DOI: 10.1002/anie.201509218
  67. Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes.
    1. Hojoh, K.; Shido, Y.; Nagao, K.; Mori, S.; Ohmiya, H.; Sawamura, M.
    2. Tetrahedron 2015, 71, 6519–6533.
    3. DOI: 10.1016/j.tet.2015.05.048
  68. Copper-Catalyzed γ-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes.
    1. Yasuda, Y.; Nagao, K.; Shido, Y.; Mori, S.; Ohmiya, H.; Sawamura, M.
    2. Chem. Eur. J. 2015, 21, 9666–9670.
    3. DOI: 10.1002/chem.201501055
  69. Copper(I)-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Alkenes.
    1. Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2015, 17, 2039–2041.
    3. DOI: 10.1021/acs.orglet.5b00758
  70. Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis.
    1. Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2015, 17, 1304–1307.
    3. DOI: 10.1021/acs.orglett.5b00305
  71. Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles.
    1. Harada, A.; Makida, Y.; Sato, T.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2014, 136, 13932–13939.
    3. DOI: 10.1021/ja5084333
  72. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes.
    1. Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2014, 136, 10605–10608.
    3. DOI: 10.1021/ja506310v
  73. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes.
    1. Hojoh, K.; Shido,Y.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2014, 53, 4954–4958 (Hot Paper).
    3. DOI: 10.1002/anie.201402386
  74. Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling with Alkylboranes, Alkynoates, and Tributyltin Methoxide.
    1. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2013, 52, 11620–11623.
    3. DOI: 10.1002/anie.201305973
  75. Cooperative Catalysis of Metal and O-H・・・O/sp3-C-H・・・O Two-point Hydrogen Bonds in Alcoholic Solvents: Copper-catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes.
    1. Ishii, T.; Watanabe, R.; Moriya, T.; Ohmiya, H,; Mori, S.; Sawamura, M.
    2. Chem. Eur. J. 2013, 19, 13547–13553.
    3. DOI: 10.1002/chem.201301280
  76. Copper-Catalyzed γ-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes.
    1. Makida, Y.; Takayama, Y.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2013, 52, 5350–5354.
    3. DOI: 10.1002/anie.201300785
  77. Use of a Semihollow-Shaped Triethynylphosphane Ligand for Efficient Formation of Six- and Seven-Membered Ring Ethers through Gold(I)-Catalyzed Cyclization of Hydroxy-Tethered Propargylic Esters.
    1. Ito, H.; Harada, A.; Ohmiya, H.; Sawamura, M.
    2. Adv. Synth. Catal. 2013, 355, 647–652.
    3. DOI: 10.1002/adsc.201200949
  78. Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes.
    1. Shido, Y.; Yoshida M.; Tanabe, M.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2012, 134, 18573–18576.
    3. DOI: 10.1021/ja3093955
  79. Conjugate Reduction of α,β-Unsaturated Carbonyl and Carboxyl Compounds with Poly(methylhydrosiloxane) Catalyzed by a Silica-Supported Compact Phosphane-Copper Complex.
    1. Kawamorita, S.; Yamazaki, K.; Ohmiya, H.; Iwai, T.; Sawamura, M. Adv. Synth. Catal. 2012, 354, 3440–3444.
    2. DOI: 10.1002/adsc.201200555
  80. Rh-Catalyzed Borylation of N-Adjacent C(sp3)-H Bonds with a Silica-Supported Triarylphosphine Ligand.
    1. Kawamorita, S.; Miyazaki, T.; Iwai, T.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2012, 134, 12924–12927.
    3. DOI: 10.1021/ja305694r
  81. Synthesis of Allenylsilanes through Copper-Catalyzed γ-Selective Coupling between γ-Silylated Propargylic Phosphates and Alkylboranes.
    1. Yokobori, U.; Ohmiya, H.; Sawamura, M.
    2. Organometallics 2012, 31, 7909–7913.
    3. DOI: 10.1021/om300552f
  82. Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper-N-Heterocyclic Carbene Complex.
    1. Yoshida, M.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2012, 134, 11896–11899.
    3. DOI: 10.1021/ja304481a
  83. Reversible 1,3-Anti/Syn Stereochemical Courses in Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes.
    1. Nagao, K.; Yokobori, U.; Makida, Y.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2012, 134, 8982–8987.
    3. DOI: 10.1021/ja302520h
  84. Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes.
    1. Nagao, K.; Ohmiya, H.; Sawamura, M.
    2. Synthesis 2012, 44, 1535–1541.
    3. DOI: 10.1055/s-0031-1290818
  85. Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation.
    1. Makida, Y.; Ohmiya, H.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2012, 51, 4122–4127.
    3. DOI: 10.1002/anie.201200809
  86. Synthesis of Conjugated Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates.
    1. Yang, M.; Yokokawa, N.;Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2012, 14, 816–819.
    3. DOI: 10.1021/ol2033465
  87. Efficient Preparation of β-Branched γ,δ -Unsaturated Esters through Copper-Catalyzed Allylic Alkylation of Ketene Silyl Acetal.
    1. Li, D.; Ohmiya, H.; Sawamura, M. Synthesis 2012, 44, 1304–1307.
    2. DOI: 10.1055/s-0031-1289712
  88. Rh-Catalyzed Ortho-Selective C-H Borylation of N-Functionalized Arenes with Silica-Supported Bridgehead Monophosphine Ligands.
    1. Kawamorita, S.; Miyazaki, T.; Ohmiya, H.; Iwai, T.; Sawamura, M.
    2. J. Am. Chem. Soc. 2011, 133, 19310–19313.
    3. DOI: 10.1021/ja208364a
  89. General Approach to Allenes through Copper-Catalyzed gannma γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Alkylboranes.
    1. Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M.
    2. Org. Lett. 2011, 13, 6312–6315.
    3. DOI: 10.1021/ol202866h
  90. Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with Silica-Supported Compact Phosphane Ligand.
    1. Kawamorita, S.; Ohmiya, H.; Iwai, T.; Sawamura, M.
    2. Angew. Chem. Int. Ed. 2011, 50, 8363–8366 (VIP).
    3. DOI: 10.1002/anie.201103224
  91. Intramolecular Hydroamination of Alkynic Sulfonamides Catalyzed by Gold-Triethynylphosphine Complex: Construction of Azepine Frameworks by 7-Exo-dig Cyclization.
    1. Ito, H.; Harada, T.; Ohmiya, H.; Sawamura, M.
    2. Beilstein. J. Org. Chem. 2011, 7, 951–959.
    3. DOI: 10.3762/bjoc.7.106
  92. Copper-Catalyzed Conjugate Additions of Alkylboranes to Aryl α,β-Unsaturated Ketones.
    1. Ohmiya, H.; Shido, Y.; Yoshida, M.; Sawamura, M.
    2. Chem. Lett. 2011, 40, 928–930.
    3. DOI: 10.1246/cl.2011.928
  93. Copper-Catalyzed γ-Selective and Stereospecific Allylic Alkylation of Ketene Silyl Acetals.
    1. Li, D.; Ohmiya, H.; Sawamura, M.
    2. J. Am. Chem. Soc. 2011, 133, 5672–5675.
    3. DOI: 10.1021/ja111645q
  94. Copper-Catalyzed Carboxylation of Alkylboranes with Carbon Dioxide: Formal Reductive Carboxylation of Terminal Alkenes.
    1. Ohmiya, H.; Tanabe, M.; Sawamura, M.
    2. Org. Lett. 2011, 13, 1086–1088.
    3. DOI: 10.1021/ol103128x
  95. Copper-Catalyzed Conjugate Additions of Alkylboranes to Imidazolyl α,β-Unsaturated Ketones: Formal Reductive Conjugate Addition of Terminal Alkenes.
    1. Ohmiya, H.; Yoshida, M.; Sawamura, M.
    2. Org. Lett. 2011, 13, 482–485.
    3. DOI: 10.1021/ol102819k
  96. Sulfonamidoquinoline-Palladium(II) Dimer Complex As a Catalyst Precursor for Palladium-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling Reaction between Allylic Acetates and Arylboronic Acids.
    1. Makida, Y.; Ohmiya, H.; Sawamura, M.
    2. Chem. Asian J. 2011, 6, 410–414.
    3. DOI: 10.1002/asia.201000721
  97. Construction of Methylenecycloheptane Frameworks through 7-Exo-dig Cyclization of Acetylenic Silyl Enol Ethers Catalyzed by Triethynylphosphine-Gold Complex.
    1. Ito, H.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2010, 12, 4380–4383.
    3. DOI: 10.1021/ol101860j
  98. Directed Ortho Borylation of Phenol Derivatives Catalyzed by a Silica-Supported Iridium Complex.
    1. Yamazaki, K.; Kawamorita, S.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2010, 12, 3978–3981.
    3. DOI: 10.1021/ol101493m
  99. Protecting-Group-Free Route to Hydroxylated Pyrrolidine and Piperidine Derivatives through Cu(I)-Catalyzed Intramolecular Hydroamination of Alkenes.
    1. Ohmiya, H.; Yoshida, M.; Sawamura, M.
    2. Synlett 2010, 2136–2140.
    3. DOI: 10.1055/s-0030-1258527
  100. Synthesis of α-Arylated Allylsilanes through Palladium-Catalyzed γ-Selective Allyl-Aryl Coupling.
    1. Li, D.; Tanaka, T.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2010, 12, 3344–3347.
    3. DOI: 10.1021/ol101114r
  101. Copper-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling between (Z)-Acyclic and Cyclic Allylic Phosphates and Arylboronates.
    1. Ohmiya, H.; Yokokawa, N.; Sawamura, M.
    2. Org. Lett. 2010, 12, 2438–2440.
    3. DOI: 10.1021/ol100841y
  102. Ester-Directed Regioselective Borylation of Heteroarenes Catalyzed by a Silica-Supported Iridium Complex.
    1. Kawamorita, S.; Ohmiya, H.; Sawamura, M.
    2. J. Org. Chem. 2010, 75, 3855–3858.
    3. DOI: 10.1021/jo100352b
  103. Selective Synthesis of Allenes and Alkynes through Ligand-Controlled, Palladium-Catalyzed Decarboxylative Hydrogenolysis of Propargylic Formates.
    1. Ohmiya, H.; Yang, M.; Yamauchi, Y.; Ohtsuka, Y.; Sawamura, M.
    2. Org. Lett. 2010, 12, 1796–1799.
    3. DOI: 10.1021/ol100405k
  104. Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes.
    1. Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M.
    2. J. Am. Chem. Soc. 2010, 132, 2895–2897.
    3. DOI: 10.1021/ja9109105
  105. Palladium-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling between Acyclic Allylic Esters and Arylboronic Acids.
    1. Ohmiya, H.; Makida, Y.; Li, D.; Tanabe, M.; Sawamura, M.
    2. J. Am. Chem. Soc. 2010, 132, 879–889.
    3. DOI: 10.1021/ja9092264
  106. General and Functional Group-Tolerable Approach to Allenylsilanes by Rhodium-Catalyzed Coupling between Propargylic Carbonates and a Silylboronate.
    1. Ohmiya, H.; Ito, H.; Sawamura, M.
    2. Org. Lett. 2009, 11, 5618–5620.
    3. DOI: 10.1021/ol902339a
  107. Cu(I)-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes Bearing a Primary or Secondary Amino Group in Alcoholic Solvents.
    1. Ohmiya, H.; Moriya, T.; Sawamura, M.
    2. Org. Lett. 2009, 11, 2145–2147.
    3. DOI: 10.1021/ol9007712
  108. Directed ortho-Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine-Iridium System.
    1. Kawamorita, S.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M.
    2. J. Am. Chem. Soc. 2009, 131, 5058–5059.
    3. DOI: 10.1021/ja9008419
  109. Palladium-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling between Allylic Acetates and Arylboronic Acids.
    1. Ohmiya, H.; Makida, Y.; Tanaka, T.; Sawamura, M.
    2. J. Am. Chem. Soc. 2008, 130, 17276–17277.
    3. DOI: 10.1021/ja808673n
  110. Cyclization of Non-Terminal Alkynic β-Keto Esters Catalyzed by Gold(I) Complex with a Semihollow, End-Capped Triethynylphosphine Ligand.
    1. Ito, H.; Makida, Y.; Ochida, A.; Ohmiya, H.; Sawamura, M.
    2. Org. Lett. 2008, 10, 5051–5054.
    3. DOI: 10.1021/ol802079r
  111. Synthesis of Silica-Supported Compact Phosphines and Their Application to Rhodium-Catalyzed Hydrosilylation of Hindered Ketones with Triorganosilanes.
    1. Hamasaka, G.; Kawamorita, S.; Ochida, A.; Akiyama, R.; Hara, K.; Fukuoka, A.; Asakura, K.; Chun, W. J.; Ohmiya, H.; Sawamura, M.
    2. Organometallics 2008, 27, 6495–6506.
    3. DOI: 10.1021/om800683g
  112. Hydrogenation of Hindered Ketones Catalyzed by a Silica-Supported Compact Phosphine-Rh System.
    1. Kawamorita, S.; Hamasaka, G.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M.
    2. Org. Lett. 2008, 10, 4697–4700.
    3. DOI: 10.1021/ol801996r
  113. Synthesis, Properties and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane.
    1. Ochida, A.; Hamasaka, G.; Yamauchi, Y.; Kawamorita, S.; Oshima, N.; Hara, K.; Ohmiya, H.; Sawamura, M.
    2. Organometallics 2008, 27, 5494–5503.
    3. DOI: 10.1021/om8005728
  114. Cobalt-Catalyzed Regioselective Dehydrohalogenation of Alkyl Halides with Dimethylphenylsilylmethylmagnesium Chloride.
    1. Kobayashi, T.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. J. Am. Chem. Soc. 2008, 130, 11276–11277.
    3. DOI: 10.1021/ja804277x
  115. Silver-Catalyzed Benzylation and Allylation Reactions of Alkyl Halides with Grignard Reagents.
    1. Someya, H.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Org. Lett. 2008, 10, 969–971.
    3. DOI: 10.1021/ol800038a
  116. Generation of Rhodium Enolates via Retro-Aldol Reaction and Its Application to Regioselective Aldol Reaction.
    1. Murakami, K.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Tetrahedron Lett. 2008, 49, 2388–2390.
    3. DOI: 10.1016/j.tetlet.2008.02.062
  117. Alpha Olefins as Alkenylmetal Equivalents in Catalytic Conjugate Addition Reactions.
    1. Ho, C.-Y.; Ohmiya, H.; Jamison, T. F.
    2. Angew. Chem. Int. Ed. 2008, 47, 1893–1895.
    3. DOI: 10.1002/anie.200705163
  118. N-Heterocyclic Carbene Ligands in Cobalt-Catalyzed Sequential Cyclization/Cross-Coupling Reactions of 6-Halo-1-hexene Derivatives with Grignard Reagents.
    1. Someya, H.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Org. Lett. 2007, 9, 1565–1567.
    3. DOI: 10.1021/ol070392f
  119. Cobalt-Catalyzed Sequential Cyclization/Cross-Coupling Reactions of 6-Halo-1-hexene Derivatives with Grignard Reagents and Their Application to the Synthesis of 1,3-Diols.
    1. Someya, H.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Tetrahedron 2007, 63, 8609–8618.
    3. DOI: 10.1016/j.tet.2007.04.083
  120. Chromium-Catalyzed Arylmagnesiation of Alkynes.
    1. Murakami, K.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Org. Lett. 2007, 9, 1569–1571.
    3. DOI: 10.1021/ol0703938
  121. Nickel-Catalyzed Carbometalation Reactions of [2-(1-Propynyl)phenyl]methanol with 1-Alkenylmagnesium Reagents.
    1. Murakami, K.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Chem. Lett. 2007, 36, 1066–1067.
    3. DOI: 10.1246/cl.2007.1066
  122. A New Approach to 4-Aryl-1,3-butanediols by Cobalt-Catalyzed Sequential Radical Cyclization/Arylation Reaction of Silicon-tethered 6-Iodo-1-hexene Derivatives.
    1. Someya, H.; Kondoh, A.; Sato, A.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Synlett 2006, 18, 3061–3064.
    3. DOI: 10.1055/s-2006-951508
  123. Cobalt(diamine)-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Arylmagnesium Reagents: Stereoselective Constructions of Arylated Asymmetric Carbons and Application to Total Synthesis of AH13205.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. J. Am. Chem. Soc. 2006, 128, 1886–1889.
    3. DOI: 10.1021/ja057560o
  124. Cobalt-Mediated Cross-Coupling Reactions of Primary and Secondary Alkyl Halides with 1-Trimethylsilylethenyl- and 2-Trimethylsilylethynylmagnesium Reagents.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Org. Lett. 2006, 8, 3093–3096.
    3. DOI: 10.1021/ol0611144
  125. Cobalt-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Aryl Grignard Reagents and Their Application to Sequential Radical Cyclization/Cross-Coupling Reactions.
    1. Ohmiya, H.; Wakabayashi, K.; Yorimitsu, H.; Oshima, K.
    2. Tetrahedron 2006, 62, 2207–2213.
    3. DOI: 10.1016/j.tet.2005.12.013
  126. Cobalt-Catalyzed Trimethylsilylmethylmagnesium-Promoted Radical Alkenylation of Alkyl Halides: A Complement to the Heck Reaction.
    1. Affo, W.; Ohmiya, H.; Fujioka, T.; Ikeda, Y.; Nakamura, T.; Yorimitsu, H.; Oshima, K.; Imamura, Y.; Mizuta, T.; Miyoshi, K.
    2. J. Am. Chem. Soc. 2006, 128, 8068–8077.
    3. DOI: 10.1021/ja061417t
  127. Cobalt-Catalyzed Syn-Hydrophosphination of Alkynes.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Angew. Chem. Int. Ed. 2005, 44, 2368–2370.
    3. DOI: 10.1002/anie.200500255
  128. Regio- and Stereoselective Approach to 1,2-Di- and 1,1,2-Trisilylethenes by Cobalt-Mediated Reaction of Silyl-Substituted Dibromomethanes with Silylmethylmagnesiums.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Angew. Chem. Int. Ed. 2005, 44, 3488–3490.
    3. DOI: 10.1002/anie.200500576
  129. Cobalt-Catalyzed Cross-Coupling Reaction of Chloropyridines with Grignard Reagents.
    1. Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    2. Chem. Lett. 2004, 33, 1240–1241.
    3. DOI: 10.1246/cl.2004.1240
  130. Cobalt-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Allylic and Benzylic Grignard Reagents and Their Application to Tandem Radical Cyclization/Cross-Coupling Reaction.
    1. Ohmiya, H.; Tsuji, T.; Yorimitsu, H.; Oshima, K. Chem. Eur. J. 2004, 10, 5640–5648.
    2. DOI: 10.1002/chem.200400545
  131. Novel Synthesis of 5-Thio-hexopyranoside: Preparation of 5-Thio-D- and L-glucose and 1,6-Anhydro-5-thio-L- and D-altrose.
    1. Uenishi, J. i.; Ohmiya, H.
    2. Tetrahedron 2003, 59, 7011–7022.
    3. DOI: 10.1016/S0040-4020(03)00864-0
  132. Studies on Stereoselective Sonogashira Coupling of 1,1-Dibromo-1-alkene.
    1. Uenishi, J. i.; Matsui, K.; Ohmiya, H.
    2. J. Organomet. Chem. 2002 , 653, 141–149.
          1. DOI: 10.1016/S0022-328X(02)01262-7

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    1. Sumida, Y.; Ohmiya, H
    2. Science of Synthesis, 2022/3: Knowledge Updates 2022/3
    3. DOI: 10.1055/sos-SD-104-00799
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    1. Sumida, Y.; Ohmiya, H.
    2. Chem. Soc. Rev. 2021, 50, 6320–6332.
    3. DOI: 10.1039/d1cs00262g
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    2. ACS Catal. 2020, 10, 6862–6869.
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    1. Ishii, T.; Nagao, K.; Ohmiya, H.
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    3. DOI: 10.1039/D0SC01538E
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    1. Ohmiya, H.; Sawamura, M.
    2. Bull. Chem. Soc. Jpn. 2020, 93, 197–203.
    3. DOI: 10.1246/bcsj.20200283
  6. N-Heterocyclic Carbene (NHC)/Metal Cooperative Catalysis
    1. Nagao, K.; Ohmiya, H. Top. Curr. Chem. 2019, 377, 35.
    2. DOI: 10.1007/s41061-019-0266-z
  7. 有機触媒で電子反応を制御する
    1. 大宮寛久
    2. ファルマシア 2020, 56, 935–937.
    3. DOI: 10.14894/faruawpsj.56.10_935
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    3. DOI: 10.1055/sos-SD-230-00048
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    2. 化学 2018, 73, 66–67.
  12. Hirohisa Ohmiya’s Author Profile
    1. Angew. Chem. Int. Ed. 2018, 57, 13718
    2. DOI: 10.1002/anie.201805108
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  18. 注目の論文「定説への挑戦」
    1. 大宮寛久
    2. 化学 2009, 64, 64–65.
  19. 海外研究室レポート「 MIT・Timothy F. Jamison 研究室」
    1. 大宮寛久
    2. Organometallic News 2009 , 85, 106–107.
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